Benchmarking the Elastic Modulus of Conjugated Polymers with Nanoindentation

IF 5.1 1区化学 Q1 POLYMER SCIENCE

Macromolecules Pub Date : 2025-03-19 DOI:10.1021/acs.macromol.4c03081

Sri Harish Kumar Paleti, Shuichi Haraguchi, Zhiqiang Cao, Mariavittoria Craighero, Joost Kimpel, Zijin Zeng, Przemyslaw Sowinski, Di Zhu, Judith Pons i Tarrés, Youngseok Kim, Qifan Li, Junda Huang, Alexei Kalaboukhov, Besira Mihiretie, Simone Fabiano, Xiaodan Gu, Christian Müller

{"title":"Benchmarking the Elastic Modulus of Conjugated Polymers with Nanoindentation","authors":"Sri Harish Kumar Paleti, Shuichi Haraguchi, Zhiqiang Cao, Mariavittoria Craighero, Joost Kimpel, Zijin Zeng, Przemyslaw Sowinski, Di Zhu, Judith Pons i Tarrés, Youngseok Kim, Qifan Li, Junda Huang, Alexei Kalaboukhov, Besira Mihiretie, Simone Fabiano, Xiaodan Gu, Christian Müller","doi":"10.1021/acs.macromol.4c03081","DOIUrl":null,"url":null,"abstract":"The elastic modulus is a critical parameter for the design of conjugated polymers for wearable electronics and correlates with electrical and thermal transport. Yet, widely different values have been reported for the same material because of the influence of processing and measurement conditions, including the temperature, mode, direction, and time scale of deformation. Thus, results obtained via different methods are usually not considered to be comparable. Here, disparate techniques from nanoindentation to tensile testing of free-standing films or films on water, buckling analysis, dynamic mechanical thermal analysis, oscillatory shear rheometry, and atomic force microscopy are compared. Strikingly, elastic modulus values obtained for the same batch of regioregular poly(3-hexylthiophene) differ by a factor of less than four, which suggests that an approximate comparison is possible. Considering the small amount of material that is typically available, nanoindentation in combination with creep analysis is identified as a reliable method for probing the elastic modulus of films with widely different elastic moduli ranging from less than 0.1 GPa in the case of a polythiophene with oligoether side chains to several GPa for polymers without side chains. Since films can display anisotropic elastic modulus values, it is proposed that nanoindentation is complemented with an in-plane technique such as tensile testing to ensure a full characterization using different modes of deformation.","PeriodicalId":51,"journal":{"name":"Macromolecules","volume":"10 1","pages":""},"PeriodicalIF":5.1000,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Macromolecules","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acs.macromol.4c03081","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}

引用次数: 0

Abstract

The elastic modulus is a critical parameter for the design of conjugated polymers for wearable electronics and correlates with electrical and thermal transport. Yet, widely different values have been reported for the same material because of the influence of processing and measurement conditions, including the temperature, mode, direction, and time scale of deformation. Thus, results obtained via different methods are usually not considered to be comparable. Here, disparate techniques from nanoindentation to tensile testing of free-standing films or films on water, buckling analysis, dynamic mechanical thermal analysis, oscillatory shear rheometry, and atomic force microscopy are compared. Strikingly, elastic modulus values obtained for the same batch of regioregular poly(3-hexylthiophene) differ by a factor of less than four, which suggests that an approximate comparison is possible. Considering the small amount of material that is typically available, nanoindentation in combination with creep analysis is identified as a reliable method for probing the elastic modulus of films with widely different elastic moduli ranging from less than 0.1 GPa in the case of a polythiophene with oligoether side chains to several GPa for polymers without side chains. Since films can display anisotropic elastic modulus values, it is proposed that nanoindentation is complemented with an in-plane technique such as tensile testing to ensure a full characterization using different modes of deformation.

Abstract Image

查看原文本刊更多论文

求助全文

约1分钟内获得全文求助全文

来源期刊

Macromolecules 工程技术-高分子科学

CiteScore

9.30

自引率

16.40%

发文量

942

审稿时长

2 months

期刊介绍： Macromolecules publishes original, fundamental, and impactful research on all aspects of polymer science. Topics of interest include synthesis (e.g., controlled polymerizations, polymerization catalysis, post polymerization modification, new monomer structures and polymer architectures, and polymerization mechanisms/kinetics analysis); phase behavior, thermodynamics, dynamic, and ordering/disordering phenomena (e.g., self-assembly, gelation, crystallization, solution/melt/solid-state characteristics); structure and properties (e.g., mechanical and rheological properties, surface/interfacial characteristics, electronic and transport properties); new state of the art characterization (e.g., spectroscopy, scattering, microscopy, rheology), simulation (e.g., Monte Carlo, molecular dynamics, multi-scale/coarse-grained modeling), and theoretical methods. Renewable/sustainable polymers, polymer networks, responsive polymers, electro-, magneto- and opto-active macromolecules, inorganic polymers, charge-transporting polymers (ion-containing, semiconducting, and conducting), nanostructured polymers, and polymer composites are also of interest. Typical papers published in Macromolecules showcase important and innovative concepts, experimental methods/observations, and theoretical/computational approaches that demonstrate a fundamental advance in the understanding of polymers.