A mixed isocyanide Mn(I) complex and its reduction to a metallate

IF 3.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2025-03-18 DOI:10.1039/d5dt00634a

Guilhem Claude, Mathias Ellwanger, Ritchie Hernandez, Adam Grippo, Joshua S. Figueroa, Ulrich Abram

引用次数: 0

Abstract

A stepwise ligand exchange starting from [Mn(CO)₅Br] allows the synthesis of the heteroleptic isocyanide manganese(I) complex mer,trans-[Mn(CNp-FAr^DArF2)3(CN^tBu)₂Br] (DArF = 3,5-(CF₃)₂C₆H₃), ^tBu = tert.butyl). Subsequent reduction gave the first heteroleptic isocyanide manganese(–1) complex, [K(18-crown-6)][Mn(CNp-FAr^DArF2)₃(CN^tBu)₂], exhibiting a five-coordinate, trigonal bipyramidal coordination sphere.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.