Synthesis of Poly(Itaconate)s With High Monomer Conversion Applying Emulsion Polymerization

IF 3.9 3区化学 Q2 POLYMER SCIENCE

Journal of Polymer Science Pub Date : 2025-01-14 DOI:10.1002/pol.20240414

S. Charlotte Fischer von Mollard, Nico Ueberschaar, Martin Schreiber, Frank Kamphuis, Stefan Zechel, Martin D. Hager

引用次数: 0

Abstract

Itaconic acid and its derivatives can be obtained from renewable feedstocks. However, there are only very limited applications of polymers containing itaconic acid so far. One limitation of the application of this polymer is that commonly utilized polymerization techniques lead to very low conversions of the corresponding monomers. Consequently, itaconic acid and its derivatives are generally considered difficult or poorly polymerizable monomers. The current study presents the improvement of the polymerization by applying an emulsion polymerization of itaconic acid esters, leading to very high monomer conversions with a residual monomer content of less than 1%.

Abstract Image

查看原文本刊更多论文

衣康酸及其衍生物可从可再生原料中获得。然而，迄今为止，含有衣康酸的聚合物的应用非常有限。这种聚合物的一个应用限制是，常用的聚合技术导致相应单体的转化率非常低。因此，衣康酸及其衍生物通常被认为是难聚合或聚合性差的单体。本研究介绍了通过应用衣康酸酯的乳液聚合来改进聚合的方法，从而获得非常高的单体转化率，残留单体含量低于 1%。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Journal of Polymer Science POLYMER SCIENCE-

CiteScore

6.30

自引率

5.90%

发文量

264

期刊介绍： Journal of Polymer Research provides a forum for the prompt publication of articles concerning the fundamental and applied research of polymers. Its great feature lies in the diversity of content which it encompasses, drawing together results from all aspects of polymer science and technology. As polymer research is rapidly growing around the globe, the aim of this journal is to establish itself as a significant information tool not only for the international polymer researchers in academia but also for those working in industry. The scope of the journal covers a wide range of the highly interdisciplinary field of polymer science and technology.