Enhanced Photoluminescence Emission and Thermal Stability in Pt₁Ag₃₁ nanocluster from Introduced Secondary Phosphine Oxide Functionalized ligand.

IF 3.5 3区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemistry - An Asian Journal Pub Date : 2025-03-08 DOI:10.1002/asia.202401819

Zhuoyuan Li, Chuanjun Zhou, Kaiyang Kuang, Jiahao Liu, Shuang Chen, Shan Jin, Manzhou Zhu

引用次数: 0

Abstract

Surface ligands significantly influence the optical properties and stability of metal nanoclusters. In this study, we synthesized [Pt₁Ag₃₁(S-Adm)₁₆(DPPM)₃(DPPMO)Cl₃](SbF₆)₄ (Pt₁Ag₃₁-DPPMO). Compared to [Pt₁Ag₃₁(S-Adm)₁₆(DPPM)₃Cl₃](SbF₆)₄ (Pt₁Ag₃₁), the introduction of secondary phosphine oxide ligand, DPPMO, results in Pt₁Ag₃₁-DPPMO exhibiting enhanced photoluminescent properties in both solution and solid states, as well as improved stability and electron-withdrawing ability. This work presents a novel strategy to regulate the properties of metal nanoclusters, especially enhancing photoluminescence performance and stability, through the incorporation of secondary phosphine oxide ligand.

查看原文本刊更多论文

求助全文

约1分钟内获得全文求助全文

来源期刊

Chemistry - An Asian Journal 化学-化学综合

CiteScore

7.00

自引率

2.40%

发文量

535

审稿时长

1.3 months

期刊介绍： Chemistry—An Asian Journal is an international high-impact journal for chemistry in its broadest sense. The journal covers all aspects of chemistry from biochemistry through organic and inorganic chemistry to physical chemistry, including interdisciplinary topics. Chemistry—An Asian Journal publishes Full Papers, Communications, and Focus Reviews. A professional editorial team headed by Dr. Theresa Kueckmann and an Editorial Board (headed by Professor Susumu Kitagawa) ensure the highest quality of the peer-review process, the contents and the production of the journal. Chemistry—An Asian Journal is published on behalf of the Asian Chemical Editorial Society (ACES), an association of numerous Asian chemical societies, and supported by the Gesellschaft Deutscher Chemiker (GDCh, German Chemical Society), ChemPubSoc Europe, and the Federation of Asian Chemical Societies (FACS).

Enhanced Photoluminescence Emission and Thermal Stability in Pt1Ag31 nanocluster from Introduced Secondary Phosphine Oxide Functionalized ligand.

Abstract

Enhanced Photoluminescence Emission and Thermal Stability in Pt₁Ag₃₁ nanocluster from Introduced Secondary Phosphine Oxide Functionalized ligand.