Study of DFT, Synthesis, and Nonlinear Optical Properties of a Schiff Base Compound.

IF 2.6 4区 化学 Q2 BIOCHEMICAL RESEARCH METHODS
Ghufran A Mirdan, Qusay M A Hassan, Mouayed Y Kadhum, C A Emshary, Kawkab Ali Hussein, H A Sultan, Sadiq M H Ismael, Hasanain A Abdullmajed
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引用次数: 0

Abstract

A Schiff base (LS2) compound is synthesized via a reaction of a hot ethanolic solution of (3-ethoxy salcyaldehyde) and a hot ethanolic solution of amine(methyl-4-amino benzoate). The LS2 compound is characterized via 1H and 13C NMR spectra, Mass spectrum, and FT-IR spectrum. We observed multiple diffraction patterns of a cw 473 nm laser beam from the LS2 compound caused by spatial self-phase modulation (SSPM). The nonlinear refractive index (NLRI) of the LS2 compound is estimated at the high-power input of the laser beam and found equals to 5.387 × 10-7 cm2/W. The Z-scan techniques are used to estimate the NLRI and found equals to 0.12 × 10-7 cm2/W. The all-optical switching (AOS) effect can be seen when 473 nm is used as the controlling beam and 532 nm is used as the controlled beam.

席夫碱化合物的DFT、合成及非线性光学性质研究。
通过(3-乙氧基水杨醛)热乙醇溶液和胺(4-氨基苯甲酸甲酯)热乙醇溶液的反应,合成了一种希夫碱(LS2)化合物。通过1H和13C NMR、质谱和FT-IR对LS2化合物进行了表征。我们观察到了由空间自相位调制(SSPM)引起的连续波473 nm LS2激光光束的多重衍射图样。在高功率激光输入下,LS2化合物的非线性折射率(NLRI)为5.387 × 10-7 cm2/W。z扫描技术用于估计NLRI,发现等于0.12 × 10-7 cm2/W。以473 nm为控制光束和532 nm为控制光束时,可以看到全光开关(AOS)效应。
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来源期刊
Journal of Fluorescence
Journal of Fluorescence 化学-分析化学
CiteScore
4.60
自引率
7.40%
发文量
203
审稿时长
5.4 months
期刊介绍: Journal of Fluorescence is an international forum for the publication of peer-reviewed original articles that advance the practice of this established spectroscopic technique. Topics covered include advances in theory/and or data analysis, studies of the photophysics of aromatic molecules, solvent, and environmental effects, development of stationary or time-resolved measurements, advances in fluorescence microscopy, imaging, photobleaching/recovery measurements, and/or phosphorescence for studies of cell biology, chemical biology and the advanced uses of fluorescence in flow cytometry/analysis, immunology, high throughput screening/drug discovery, DNA sequencing/arrays, genomics and proteomics. Typical applications might include studies of macromolecular dynamics and conformation, intracellular chemistry, and gene expression. The journal also publishes papers that describe the synthesis and characterization of new fluorophores, particularly those displaying unique sensitivities and/or optical properties. In addition to original articles, the Journal also publishes reviews, rapid communications, short communications, letters to the editor, topical news articles, and technical and design notes.
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