Salt Metathesis: An Ultimate Click Reaction⊥

Precision Chemistry Pub Date : 2024-11-20 DOI:10.1021/prechem.4c0008810.1021/prechem.4c00088

Christopher M. Butch, Patrick C. Hillesheim* and Arsalan Mirjafari*,

引用次数: 0

Abstract

In this Comment, we suggest salt metathesis (or ion exchange) as an ultimate click reaction, extending click chemistry principles beyond covalent bonds to ionic interactions. These universal and robust reactions, which nature utilizes in marine organisms' biomineralization processes, proceed spontaneously under mild conditions with minimal waste, embodying the core principles of click philosophy. This perspective expands the traditional scope of click chemistry and opens new opportunities in synthetic accessibility across organic, inorganic, and materials science spaces.

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Salt meta：一种终极的点击反应

在这篇评论中，我们认为盐的复分解（或离子交换）是一种最终的咔嗒反应，将咔嗒化学原理从共价键扩展到离子相互作用。自然界在海洋生物的生物矿化过程中利用这些普遍而强大的反应，在温和的条件下自发进行，浪费最少，体现了点击哲学的核心原则。这一观点扩展了传统的点击化学的范围，并为有机、无机和材料科学领域的合成可达性开辟了新的机会。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Precision Chemistry 精密化学技术-

CiteScore

0.80

自引率

0.00%

发文量

期刊介绍： Chemical research focused on precision enables more controllable predictable and accurate outcomes which in turn drive innovation in measurement science sustainable materials information materials personalized medicines energy environmental science and countless other fields requiring chemical insights.Precision Chemistry provides a unique and highly focused publishing venue for fundamental applied and interdisciplinary research aiming to achieve precision calculation design synthesis manipulation measurement and manufacturing. It is committed to bringing together researchers from across the chemical sciences and the related scientific areas to showcase original research and critical reviews of exceptional quality significance and interest to the broad chemistry and scientific community.