Lewis acids in the synthesis of naphthoquinonylbenzo[g]chromenediones, derivatives of mesocentroquinone, a metabolite of the sea urchins Mesocentrotus nudus and Strongylocentrotus intermedius

IF 1.7 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Russian Chemical Bulletin Pub Date : 2025-02-20 DOI:10.1007/s11172-024-4489-y

K. L. Borisova, D. N. Pelageev, V. Ph. Anufriev

引用次数: 0

Abstract

An approach was developed for the synthesis of naphthoquinonylbenzo[g]chromenedions, derivatives of mesocentroquinone, a metabolite of the sea urchins Mesocentrotus nudus and Strongylocentrotus intermedius. The key stage in the developed approach is the previously undescribed heterodiene condensation of 2-oxo-3-alkylidene- and 3-alkenyl-2-hydroxy-1,4-naphthoquinones formed during dehydrobromination of the corresponding 3-(1-bromoalkyl)-2-hydroxy derivatives in the presence of Lewis acid (SnCl₄).

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来源期刊

Russian Chemical Bulletin 化学-化学综合

CiteScore

2.70

自引率

47.10%

发文量

257

审稿时长

3-8 weeks

期刊介绍： Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.