Quinuclidine-Catalyzed Electrochemical Minisci Acylation of N-Heteroarenes with Acylhydrazines

IF 3.8 3区化学 Q2 CHEMISTRY, PHYSICAL

ChemCatChem Pub Date : 2024-12-03 DOI:10.1002/cctc.202401642

Haonan Zhang, Dehui Wang, Prof. Kun Xu, Prof. Chengchu Zeng

引用次数: 0

Abstract

The quinuclidine (Qu)-catalyzed activation of acylhydrazines to afford the corresponding acyl radicals remains an unmet challenge. To address this challenge, we report a synergistic strategy by combining electro-oxidation with Qu-based HAT catalysis. Enabled by this strategy, the electrochemical Minisci acylation of N-heterocycles with acylhydrazines was realized for the first time.

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来源期刊

ChemCatChem 化学-物理化学

CiteScore

8.10

自引率

4.40%

发文量

511

审稿时长

1.3 months

期刊介绍： With an impact factor of 4.495 (2018), ChemCatChem is one of the premier journals in the field of catalysis. The journal provides primary research papers and critical secondary information on heterogeneous, homogeneous and bio- and nanocatalysis. The journal is well placed to strengthen cross-communication within between these communities. Its authors and readers come from academia, the chemical industry, and government laboratories across the world. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies, and is supported by the German Catalysis Society.