Chemical and Electrochemical Oxidation of Diferrocenyltelluride

IF 2.2 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

European Journal of Inorganic Chemistry Pub Date : 2025-01-10 DOI:10.1002/ejic.202400709

Corina Stoian, Nils Schmidt, Pim Puylaert, Mathias H. Linden, H. Bernhard Linden, Jens Beckmann

引用次数: 0

Abstract

The halogenation of diferrocenyltelluride, Fc₂Te, with XeF₂, PhICl₂ and I₂ afforded the diferrocenyltellurium dihalides Fc₂TeX₂ (X=F, Cl, I). Halide exchange of Fc₂TeCl₂ with KBr yielded Fc₂TeBr₂. The oxidation of Fc₂Te with NO[SbF₆] and K[B(C₆F₅)₄] provided the triferrocenyltelluronium salt [Fc₃Te][B(C₆F₅)₄] and the dinuclear nitrosyl iron complex Fe₂(μ-TeFc)₂(NO)₄. The new compounds were comprehensively characterized by multinuclear NMR spectroscopy (¹²⁵Te, ¹⁹F, ¹³C, ¹H), UV/vis absorption spectroscopy, cyclic voltammetry, LIFDI-TOF mass spectrometry and single crystal X-ray diffraction.

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二茂铁碲化物的化学和电化学氧化

二茂铁碲化物Fc2Te与XeF2、PhICl2和I2卤化得到二茂铁碲化物Fc2TeX2 (X=F, Cl， I)， Fc2TeCl2与KBr卤化交换得到Fc2TeBr2。用NO[SbF6]和K[B(C6F5)4]氧化Fc2Te得到三氰基碲铵盐[Fc3Te][B(C6F5)4]和双核亚硝基铁配合物Fe2(μ-TeFc)2(NO)4。采用多核核磁共振（125Te, 19F, 13C, 1H）、紫外/可见吸收光谱、循环伏安法、LIFDI-TOF质谱和单晶x射线衍射对化合物进行了全面表征。

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来源期刊

European Journal of Inorganic Chemistry 化学-无机化学与核化学

CiteScore

4.30

自引率

4.30%

发文量

419

审稿时长

1.3 months

期刊介绍： The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry: Chemische Berichte Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.