Access to SCF3-containing N-fused quinolines via photo-induced domino radical trifluoromethylthiolation

IF 6.5 1区化学 Q2 CHEMISTRY, PHYSICAL

Journal of Catalysis Pub Date : 2025-02-13 DOI:10.1016/j.jcat.2025.116005

Congjun Zhu, Yangyang Shen, Zilong Wang, Jie Xu, Wendong Fang, Haofang Tian, Jinjie Li, Tao Guo

引用次数: 0

Abstract

Radical trifluoromethylthiolation under mild photoredox conditions, show unique utility in the preparation of SCF₃-containing organic skeleton. Here, we report an unprecedented domino radical trifluoromethylthiolation upon photocatalysis. With the established protocol, a wide spectrum of SCF₃-containing N-fused quinolines has been rapidly synthesized. Preliminary mechanistic investigations, including several control experiments and photochemistry measurements, shed light on the catalytic radical reaction mechanism. Sequential evaluated the photophysical properties for selected products is presented, which further underlines the value of this work.

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来源期刊

Journal of Catalysis 工程技术-工程：化工

CiteScore

12.30

自引率

5.50%

发文量

447

审稿时长

31 days

期刊介绍： The Journal of Catalysis publishes scholarly articles on both heterogeneous and homogeneous catalysis, covering a wide range of chemical transformations. These include various types of catalysis, such as those mediated by photons, plasmons, and electrons. The focus of the studies is to understand the relationship between catalytic function and the underlying chemical properties of surfaces and metal complexes. The articles in the journal offer innovative concepts and explore the synthesis and kinetics of inorganic solids and homogeneous complexes. Furthermore, they discuss spectroscopic techniques for characterizing catalysts, investigate the interaction of probes and reacting species with catalysts, and employ theoretical methods. The research presented in the journal should have direct relevance to the field of catalytic processes, addressing either fundamental aspects or applications of catalysis.