Recent Advances in ZIF Membrane: Fabrication, Separation Ability and Its Application.

Abstract

With the growth of the population and the development of industry and agriculture, water resources are experiencing contamination by numerous pollutants, posing a threat to the aquatic environment and human health. Zeolitic imidazolate framework (ZIF) membranes, as a solution for water pollutant treatment, not only have the advantages of high efficiency adsorption, good selectivity, stability, and easy recyclability, but they also can be modified or derivatized through surface functionalization, compositing, or structural tuning, which can further endow the membranes with other functions, such as catalysis and degradation. In order to improve the performance of ZIF membranes, it is crucial to select suitable preparation methods to optimize the microstructure of the membranes and to improve the separation performance and stability of the membranes. This review systematically summarizes the current major preparation methods of ZIF membranes and their respective advantages and disadvantages, providing an overview of the applications of ZIF membranes in the treatment of water pollutants, such as dyes, antibiotics, and heavy metal ions. Future development prospects are also discussed, with the expectation that future research will optimize the synthesis methods to enhance the mechanical strength of the membranes and improve their selectivity, permeability, and anti-fouling properties through modifications or functionalization. This article is expected to provide theoretical support for the application of ZIF membranes in water pollution treatment.