Auto-Tandem Catalyst: From Allylic Alcohols to Secondary Alcohols via Redox Isomerization/Atmospheric Hydrogenation in Water Catalyzed by a Water-Soluble Iridium Complex Bearing a Functional Ligand

IF 4.3 2区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Inorganic Chemistry Pub Date : 2025-02-13 DOI:10.1021/acs.inorgchem.4c04283

Xiaozhong Chen, Beixuan Dong, Guoqiang Zhao, Jing Xu, Feng Li

引用次数: 0

Abstract

A water-soluble iridium complex [Cp*Ir(6,6′-(OH)₂-2,2′-bpy)(H₂O)][OTf]₂ was found to be an efficient autotandem catalyst for the synthesis of secondary alcohols via redox isomerization/atmospheric hydrogenation in water. The OH groups in the bpy ligand are a key factor for the activity of the catalyst. Then, the mechanistic experiments and the practical utilization of the catalytic system were presented.

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来源期刊

Inorganic Chemistry 化学-无机化学与核化学

CiteScore

7.60

自引率

13.00%

发文量

1960

审稿时长

1.9 months

期刊介绍： Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.