A Novel Electrochemical Platform Based on Cadmium (II) (fluorophenyl)Porphyrin and Gold Nanoparticles Modified Screen-Printed Electrode Electrode for the Sensitive Detection of Bisphenol A

IF 2.7 3区化学 Q2 CHEMISTRY, ANALYTICAL

Electroanalysis Pub Date : 2025-02-07 DOI:10.1002/elan.12017

Fatma Rejab, Nour Elhouda Dardouri, Ahlem Rouis, Mosaab Echabaane, Habib Nasri, Hamdi Ben Halima, Nicole Jaffrezic-Renault

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引用次数: 0

Abstract

Bisphenol A (BPA) is categorized as an endocrine-disrupting substance; it is a risky substance to both environmental and human health, necessitating monitoring. In this present study, a novel electrochemical sensing platform based on Cd metalloporphyrin ([(5,10,15,20- tetrakis(p-flurophenyl) porphyrinato] cadmium (II) [CdTFPP]) and gold nanoparticles (AuNPs) for a rapid and sensitive determination of BPA was designed. To confirm the successful synthesis of CdTFPP, UV/vis, IR, and ¹H NMR were employed. The detection platform CdTFPP/AuNPs/SPCE was prepared using a screen-printed electrode (SPCE), through the deposition of AuNPs and CdTFPP by drop-casting. Under optimized measuring conditions, the developed sensor exhibited two linear ranges from 10⁻¹⁰ to 10⁻⁷ M and 10⁻⁷ to 10⁻² M with a limit of detection of 133 pM. Additionally, the CdTFPP/AuNPs/SPCE/ electrode demonstrated to present an excellent selectivity and reproducibility and to be a promising tool for the development of simple low-cost water quality monitoring system for BPA detection.

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来源期刊

Electroanalysis 化学-电化学

CiteScore

6.00

自引率

3.30%

发文量

222

审稿时长

2.4 months

期刊介绍： Electroanalysis is an international, peer-reviewed journal covering all branches of electroanalytical chemistry, including both fundamental and application papers as well as reviews dealing with new electrochemical sensors and biosensors, nanobioelectronics devices, analytical voltammetry, potentiometry, new electrochemical detection schemes based on novel nanomaterials, fuel cells and biofuel cells, and important practical applications. Serving as a vital communication link between the research labs and the field, Electroanalysis helps you to quickly adapt the latest innovations into practical clinical, environmental, food analysis, industrial and energy-related applications. Electroanalysis provides the most comprehensive coverage of the field and is the number one source for information on electroanalytical chemistry, electrochemical sensors and biosensors and fuel/biofuel cells.