Andrey I. Bazlov, Evgeny V. Ubyivovk, Ilya V. Strochko, Erzhena N. Zanaeva, Tatiana A. Sviridova
{"title":"Influence of small additions of aluminum on the structure and phase composition of (Fe0.25Co0.25Ni0.25Cr0.125V0.125)83B17 alloy","authors":"Andrey I. Bazlov, Evgeny V. Ubyivovk, Ilya V. Strochko, Erzhena N. Zanaeva, Tatiana A. Sviridova","doi":"10.1007/s11015-024-01840-0","DOIUrl":null,"url":null,"abstract":"<div><p>This work investigates the influence of small additions of aluminum on the structure of ingots from a high-entropy alloy of the (Fe<sub>0.25</sub>Co<sub>0.25</sub>Ni<sub>0.25</sub>Cr<sub>0.125</sub>V<sub>0.125</sub>)<sub>83</sub>B<sub>17</sub> composition. The structure of experimental alloys was analyzed using scanning electron microscopy and EDX analysis. The borides formed in the structure were analyzed by transmission electron microscopy, X‑ray diffraction, and electron backscatter diffraction. Aluminum addition was found to change the crystallization process of the alloys, affecting the type of primary boride crystals and eutectic composition. The addition of aluminum to the alloy in greater amounts changes the boride type from refractory boride of (V, Cr)B type to a more easily melting type of boride M<sub>3</sub>B<sub>2</sub>.</p></div>","PeriodicalId":702,"journal":{"name":"Metallurgist","volume":"68 9","pages":"1293 - 1301"},"PeriodicalIF":0.8000,"publicationDate":"2025-01-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Metallurgist","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s11015-024-01840-0","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
引用次数: 0
Abstract
This work investigates the influence of small additions of aluminum on the structure of ingots from a high-entropy alloy of the (Fe0.25Co0.25Ni0.25Cr0.125V0.125)83B17 composition. The structure of experimental alloys was analyzed using scanning electron microscopy and EDX analysis. The borides formed in the structure were analyzed by transmission electron microscopy, X‑ray diffraction, and electron backscatter diffraction. Aluminum addition was found to change the crystallization process of the alloys, affecting the type of primary boride crystals and eutectic composition. The addition of aluminum to the alloy in greater amounts changes the boride type from refractory boride of (V, Cr)B type to a more easily melting type of boride M3B2.
期刊介绍:
Metallurgist is the leading Russian journal in metallurgy. Publication started in 1956.
Basic topics covered include:
State of the art and development of enterprises in ferrous and nonferrous metallurgy and mining;
Metallurgy of ferrous, nonferrous, rare, and precious metals; Metallurgical equipment;
Automation and control;
Protection of labor;
Protection of the environment;
Resources and energy saving;
Quality and certification;
History of metallurgy;
Inventions (patents).