Comprehensive crystallographic engineering for high-efficiency and durable zinc metal anodes

IF 33.6 1区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Progress in Materials Science Pub Date : 2025-02-05 DOI:10.1016/j.pmatsci.2025.101453

Ziyu Peng, Xiran Shen, Binghui Li, Jiajie Cheng, Zhangxing He, Zhefei Sun, Bin Li, Zekun Zhang, Zilong Zhuang, Xianwen Wu, Lei Dai, Ling Wang, Guanjie He, Qiaobao Zhang

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引用次数: 0

Abstract

Aqueous zinc-ion batteries (AZIBs) hold significant promise for large-scale energy storage systems and wearable devices due to their high safety, acceptable energy density, and cost-effectiveness. However, AZIBs face formidable challenges, including Zn dendrites, side reactions, sluggish reaction kinetics, and shuttle effects, which lead to rapid capacity reduction and limited cycle life of Zn anodes, posing a significant barrier to their practical application. Modulating the crystal orientation on the surface of Zn anodes is an effective approach to prevent dendrite growth. Regulating the oriented deposition of Zn atoms along Zn(002) crystal planes can achieve a dendrite-free Zn anode. In addition, side reactions are reduced by the directional deposition of (002) plane. This review provides an in-depth analysis of the challenges facing Zn anodes and explores the feasibility of achieving high-performance Zn anodes through the regulation of Zn directional deposition. Comprehensive crystallographic regulation strategies are systematically summarized, including preparation strategies and designs of Zn(002) crystal plane induction. Finally, the mechanisms underlying directional deposition are thoroughly reviewed. The current limitations of Zn(002) plane-oriented deposition and future development opportunities are discussed to advance the commercial viability of AZIBs.

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来源期刊

Progress in Materials Science 工程技术-材料科学：综合

CiteScore

59.60

自引率

0.80%

发文量

101

审稿时长

11.4 months

期刊介绍： Progress in Materials Science is a journal that publishes authoritative and critical reviews of recent advances in the science of materials. The focus of the journal is on the fundamental aspects of materials science, particularly those concerning microstructure and nanostructure and their relationship to properties. Emphasis is also placed on the thermodynamics, kinetics, mechanisms, and modeling of processes within materials, as well as the understanding of material properties in engineering and other applications. The journal welcomes reviews from authors who are active leaders in the field of materials science and have a strong scientific track record. Materials of interest include metallic, ceramic, polymeric, biological, medical, and composite materials in all forms. Manuscripts submitted to Progress in Materials Science are generally longer than those found in other research journals. While the focus is on invited reviews, interested authors may submit a proposal for consideration. Non-invited manuscripts are required to be preceded by the submission of a proposal. Authors publishing in Progress in Materials Science have the option to publish their research via subscription or open access. Open access publication requires the author or research funder to meet a publication fee (APC). Abstracting and indexing services for Progress in Materials Science include Current Contents, Science Citation Index Expanded, Materials Science Citation Index, Chemical Abstracts, Engineering Index, INSPEC, and Scopus.