Ni-Fe supported on CaAl2O4 obtained from eggs shell for chemical looping technology

IF 5.6 2区工程技术 Q2 ENERGY & FUELS

Journal of The Energy Institute Pub Date : 2025-02-01 DOI:10.1016/j.joei.2024.101877

Ariklênio A. da Silva , Dulce M.A. Melo , Tiago R. da Costa , Rodolfo Luiz B.A. Medeiros , Gineide C. dos Anjos , Fabíola C. Carvalho , Rebecca A.B.N. Santiago , Ângelo A.S. Oliveira , Renata M. Braga

{"title":"Ni-Fe supported on CaAl2O4 obtained from eggs shell for chemical looping technology","authors":"Ariklênio A. da Silva , Dulce M.A. Melo , Tiago R. da Costa , Rodolfo Luiz B.A. Medeiros , Gineide C. dos Anjos , Fabíola C. Carvalho , Rebecca A.B.N. Santiago , Ângelo A.S. Oliveira , Renata M. Braga","doi":"10.1016/j.joei.2024.101877","DOIUrl":null,"url":null,"abstract":"<div><div>The development of oxygen carriers with specific properties is one of the main bottlenecks for applicability of chemical looping processes. Considering this, the article presents an investigation of the physicochemical, structural, morphological and reactive properties of four oxygen carriers based on Fe and/or Ni supported on calcium aluminate. Three different calcium aluminates were prepared: one by the conventional Pechini method, the following two using eggshell residue as calcium source, one with the shell in natura and last calcined at 500 °C. The support obtained from the eggshell in natura presented greater surface area and pore volume, being selected for continuity of the research. The active phase was added by the method of incipient wetness impregnation. XRD, TPR results showed that iron interacted with the support forming calcium ferrite, while nickel showed inert to the support. The reactivity by thermogravimetry showed that the OC Ni/CA presented practically 100 % reactivity in the cycles of reduction with methane and oxidation with air, and its structural and morphological properties remained unchanged after its regeneration.</div></div>","PeriodicalId":17287,"journal":{"name":"Journal of The Energy Institute","volume":"118 ","pages":"Article 101877"},"PeriodicalIF":5.6000,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Energy Institute","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1743967124003556","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}

引用次数: 0

Abstract

The development of oxygen carriers with specific properties is one of the main bottlenecks for applicability of chemical looping processes. Considering this, the article presents an investigation of the physicochemical, structural, morphological and reactive properties of four oxygen carriers based on Fe and/or Ni supported on calcium aluminate. Three different calcium aluminates were prepared: one by the conventional Pechini method, the following two using eggshell residue as calcium source, one with the shell in natura and last calcined at 500 °C. The support obtained from the eggshell in natura presented greater surface area and pore volume, being selected for continuity of the research. The active phase was added by the method of incipient wetness impregnation. XRD, TPR results showed that iron interacted with the support forming calcium ferrite, while nickel showed inert to the support. The reactivity by thermogravimetry showed that the OC Ni/CA presented practically 100 % reactivity in the cycles of reduction with methane and oxidation with air, and its structural and morphological properties remained unchanged after its regeneration.

Abstract Image

查看原文本刊更多论文

求助全文

约1分钟内获得全文求助全文

来源期刊

Journal of The Energy Institute 工程技术-能源与燃料

CiteScore

10.60

自引率

5.30%

发文量

166

审稿时长

16 days

期刊介绍： The Journal of the Energy Institute provides peer reviewed coverage of original high quality research on energy, engineering and technology.The coverage is broad and the main areas of interest include: Combustion engineering and associated technologies; process heating; power generation; engines and propulsion; emissions and environmental pollution control; clean coal technologies; carbon abatement technologies Emissions and environmental pollution control; safety and hazards; Clean coal technologies; carbon abatement technologies, including carbon capture and storage, CCS; Petroleum engineering and fuel quality, including storage and transport Alternative energy sources; biomass utilisation and biomass conversion technologies; energy from waste, incineration and recycling Energy conversion, energy recovery and energy efficiency; space heating, fuel cells, heat pumps and cooling systems Energy storage The journal''s coverage reflects changes in energy technology that result from the transition to more efficient energy production and end use together with reduced carbon emission.