{"title":"The chemistry of bimetallic surfaces – Evolution of an atomic-scale picture","authors":"R. Jürgen Behm, Axel Groß","doi":"10.1016/j.susc.2024.122677","DOIUrl":null,"url":null,"abstract":"<div><div>In this contribution, we will review the concepts and principles used to characterize and discuss the structure, stability, adsorption properties and catalytic reactivity of bimetallic surfaces in an atomic-scale picture. Starting from early stages, we will emphasize recent experimental and theoretical findings that resulted in a rapidly improving atomic-scale understanding of adsorption and catalytic surface reactions on these surfaces. While examples are often taken from our own work, the resulting insights are of general validity.</div></div>","PeriodicalId":22100,"journal":{"name":"Surface Science","volume":"754 ","pages":"Article 122677"},"PeriodicalIF":2.1000,"publicationDate":"2024-12-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Surface Science","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0039602824002280","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
In this contribution, we will review the concepts and principles used to characterize and discuss the structure, stability, adsorption properties and catalytic reactivity of bimetallic surfaces in an atomic-scale picture. Starting from early stages, we will emphasize recent experimental and theoretical findings that resulted in a rapidly improving atomic-scale understanding of adsorption and catalytic surface reactions on these surfaces. While examples are often taken from our own work, the resulting insights are of general validity.
期刊介绍:
Surface Science is devoted to elucidating the fundamental aspects of chemistry and physics occurring at a wide range of surfaces and interfaces and to disseminating this knowledge fast. The journal welcomes a broad spectrum of topics, including but not limited to:
• model systems (e.g. in Ultra High Vacuum) under well-controlled reactive conditions
• nanoscale science and engineering, including manipulation of matter at the atomic/molecular scale and assembly phenomena
• reactivity of surfaces as related to various applied areas including heterogeneous catalysis, chemistry at electrified interfaces, and semiconductors functionalization
• phenomena at interfaces relevant to energy storage and conversion, and fuels production and utilization
• surface reactivity for environmental protection and pollution remediation
• interactions at surfaces of soft matter, including polymers and biomaterials.
Both experimental and theoretical work, including modeling, is within the scope of the journal. Work published in Surface Science reaches a wide readership, from chemistry and physics to biology and materials science and engineering, providing an excellent forum for cross-fertilization of ideas and broad dissemination of scientific discoveries.