{"title":"Unlocking Interpretable Prediction of Battery Random Discharge Capacity With Domain Adaptative Physics Constraint","authors":"Yunhong Che, Jia Guo, Yusheng Zheng, Daniel-Ioan Stroe, Wenxue Liu, Xiaosong Hu, Remus Teodorescu","doi":"10.1002/aenm.202405506","DOIUrl":null,"url":null,"abstract":"Tracking the battery discharge capacity is significant, yet challenging due to complicated degradation patterns as well as varying or even random usage scenarios. This work proposes a physics-constrained domain adaptation framework to predict the capacities during random discharge with non-destructive mechanism diagnosis using early or random discharging information. By imposing the impedance as physical constraints in a domain adaptative layer, the interpretability and generalization of the model can be improved as the physics-constrained layer provides physical insights into the battery mechanism characteristics, enabling onboard and non-destructive diagnosis without complex tests. The learned impedances in the physics-constrained layer are well-fitted to the real ones, suggesting accurate physical insights and, therefore, good interpretability of the trained model. Furthermore, apart from capacity prediction, the aging mechanisms of the cell can be interpreted through the learned physics from this deep learning framework without impedance measurement. Such interpretation has also been validated experimentally through post-mortem analysis. This work provides an example of grey-box modeling of complex dynamic systems where deep learning models can provide certain physical details to increase the model's interpretability.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"37 1","pages":""},"PeriodicalIF":24.4000,"publicationDate":"2025-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Energy Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/aenm.202405506","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Tracking the battery discharge capacity is significant, yet challenging due to complicated degradation patterns as well as varying or even random usage scenarios. This work proposes a physics-constrained domain adaptation framework to predict the capacities during random discharge with non-destructive mechanism diagnosis using early or random discharging information. By imposing the impedance as physical constraints in a domain adaptative layer, the interpretability and generalization of the model can be improved as the physics-constrained layer provides physical insights into the battery mechanism characteristics, enabling onboard and non-destructive diagnosis without complex tests. The learned impedances in the physics-constrained layer are well-fitted to the real ones, suggesting accurate physical insights and, therefore, good interpretability of the trained model. Furthermore, apart from capacity prediction, the aging mechanisms of the cell can be interpreted through the learned physics from this deep learning framework without impedance measurement. Such interpretation has also been validated experimentally through post-mortem analysis. This work provides an example of grey-box modeling of complex dynamic systems where deep learning models can provide certain physical details to increase the model's interpretability.
期刊介绍:
Established in 2011, Advanced Energy Materials is an international, interdisciplinary, English-language journal that focuses on materials used in energy harvesting, conversion, and storage. It is regarded as a top-quality journal alongside Advanced Materials, Advanced Functional Materials, and Small.
With a 2022 Impact Factor of 27.8, Advanced Energy Materials is considered a prime source for the best energy-related research. The journal covers a wide range of topics in energy-related research, including organic and inorganic photovoltaics, batteries and supercapacitors, fuel cells, hydrogen generation and storage, thermoelectrics, water splitting and photocatalysis, solar fuels and thermosolar power, magnetocalorics, and piezoelectronics.
The readership of Advanced Energy Materials includes materials scientists, chemists, physicists, and engineers in both academia and industry. The journal is indexed in various databases and collections, such as Advanced Technologies & Aerospace Database, FIZ Karlsruhe, INSPEC (IET), Science Citation Index Expanded, Technology Collection, and Web of Science, among others.