Mechanically processed Sardinian wool promotes C–C bond synthesis under solvent-free conditions†

Sourav Behera, Federico Cuccu, Francesco Basoccu, Stefano Barranco and Andrea Porcheddu
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Abstract

The tangible environmental concerns of the last few decades are prompting science to a new sustainable paradigm for chemical reactions and a circular economy. In the present manuscript, complying with this dichotomy, Sardinian wool is presented as a promising material for organic synthesis. Aldol and nitro-aldol additions, and Knoevenagel reactions were demonstrated with high efficiency under wool-promoted and solvent-free conditions, paving the way to novel approaches for converting wool biomass waste into value-added products for C–C bond formation.

Abstract Image

机械加工的撒丁岛羊毛在无溶剂条件下促进C-C键合成†
过去几十年对环境的切实关注正促使科学转向化学反应和循环经济的新的可持续模式。在目前的手稿中,符合这种二分法,撒丁岛羊毛是一种有前途的有机合成材料。在羊毛促进和无溶剂条件下,证明了Aldol和硝基Aldol加成以及Knoevenagel反应的高效率,为将羊毛生物质废物转化为用于C-C键形成的增值产品铺平了新途径。
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