Pyrene-based, red-emitting, aggregation-induced emission luminogens: from structural construction to anti-counterfeiting applications†

IF 6 2区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Hua-Long Li, Zeng-Min Xue, Guang Yang, Fei Meng, Hong-Tao Lin, Wen-Xuan Zhao, Shu-Hai Chen and Chuan-Zeng Wang
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引用次数: 0

Abstract

Herein, we demonstrated a novel approach to construct pyrene-based, high-efficiency, red-emitting molecules. Both of the as-synthesized luminogens exhibited aggregation-induced enhanced emission (AIEE) properties and distinct mechanochromic behavior with a blue-shift for DCI-Py-1 (13 nm) and red-shift for DCI-Py-2 (29 nm). The typical, yet rare, pyrene-based, red-emitting molecules with λem = 686 nm open up new avenues to design near-infrared emitting pyrene-based photoelectric materials. Further studies revealed that both of these materials can be utilized for anti-counterfeiting stamps and fingerprint extraction.

Abstract Image

比利牛斯基,红色发光,聚集诱导发光:从结构建设到防伪应用†
在这里,我们展示了一种新的方法来构建基于芘的、高效的、发红光的分子。两种合成的发光物质均表现出聚集诱导的增强发射(AIEE)特性和明显的机械致色行为,DCI-Py-1的蓝移(13 nm)和DCI-Py-2的红移(29 nm)。典型而罕见的λem = 686 nm的芘基红发分子为设计近红外芘基光电材料开辟了新的途径。进一步的研究表明,这两种材料都可以用于防伪邮票和指纹提取。
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来源期刊
Materials Chemistry Frontiers
Materials Chemistry Frontiers Materials Science-Materials Chemistry
CiteScore
12.00
自引率
2.90%
发文量
313
期刊介绍: Materials Chemistry Frontiers focuses on the synthesis and chemistry of exciting new materials, and the development of improved fabrication techniques. Characterisation and fundamental studies that are of broad appeal are also welcome. This is the ideal home for studies of a significant nature that further the development of organic, inorganic, composite and nano-materials.
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