Construction of a Heterostructured Alloy–Molybdenum Nitride Catalyst for Enhanced NH3 Production via Nitrate Electrolysis

IF 4.7 2区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Inorganic Chemistry Pub Date : 2025-01-14 DOI:10.1021/acs.inorgchem.4c04968

Hanwen Liang, Mingying Chen, Yanhong Feng, Ge Meng, Jingwen Zhang, Wenxian Liu, Xijun Liu

引用次数: 0

Abstract

Here, we reported a highly efficient nitrate electroreduction (NO₃RR) electrocatalyst that integrated alloying and heterostructuring strategies comprising FeCo alloy and Mo_0.82N (FeCo-Mo_0.82N/NC). Notably, the maximum NH₃ Faraday efficiency (FE) of 83.24%, NH₃ yield of 12.28 mg h^–1 mg_cat.^–1, and good stability were achieved over FeCo-Mo_0.82N/NC. Moreover, a Zn-NO₃^– battery assembled with FeCo-Mo_0.82N/NC exhibited a power density of 0.87 mW cm^–2, an NH₃ yield of 14.09 mg h^–1 mg_cat.^–1, and a FE as high as 76.31%.

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构建异质结构合金-氮化钼催化剂以提高硝酸盐电解法的 NH3 产量

本文报道了一种高效的硝酸电还原（NO3RR）电催化剂，该催化剂将FeCo合金和Mo0.82N （FeCo-Mo0.82N/NC）合金化和异质化策略结合在一起。NH3的最大法拉第效率（FE）为83.24%，NH3产率为12.28 mg h-1 mgcat。-1，在FeCo-Mo0.82N/NC上具有良好的稳定性。用feo - mo0.82 n /NC组装的Zn-NO3 -电池的功率密度为0.87 mW cm-2， NH3产率为14.09 mg h-1 mgcat。-1， FE高达76.31%。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Inorganic Chemistry 化学-无机化学与核化学

CiteScore

7.60

自引率

13.00%

发文量

1960

审稿时长

1.9 months

期刊介绍： Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.