Multifunctional Properties and Potential Applications of Prussian Blue Analogue Magnets

IF 7.2 2区 材料科学 Q2 CHEMISTRY, PHYSICAL
Pramod Bhatt, Amit Kumar, S. M. Yusuf
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引用次数: 0

Abstract

PBAs (Prussian blue analogues), a fascinating class of open framework-based magnetic materials, have garnered significant attention due to their versatile crystal structure and multifunctional properties. This review article provides in-depth insight into the relationship between the unique crystal structure of PBAs and their diverse magnetic properties, such as magnetic ordering, the magnetocaloric effect, and the magnetization reversal phenomenon. The importance of the neutron scattering probe to understand the local structural disorder in PBAs is discussed in highlighting structure– (magnetic) property relations. Examples on the tuning of magnetic ordering temperature by optimizing composition through alkali metal ion insertion or by designing a core/shell type structure which promotes the magnetic proximity effect are reviewed. Besides, the electrochemical properties of PBAs, suitable for energy storage solutions, including batteries and supercapacitors, are addressed. The review also examines the usefulness of PBAs in hydrogen storage, radioactive waste management, and advanced memory devices, such as magnetic random-access memory (MRAM). Additionally, the integration of PBAs into graphene devices for spintronics and energy storage applications further highlights their potential in various technological domains. In conclusion, the remarkable versatility in structure–property relations and promising applications of PBAs offer exciting prospects for future research and development and underscore their significance in advancing materials science and technology.

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来源期刊
Chemistry of Materials
Chemistry of Materials 工程技术-材料科学:综合
CiteScore
14.10
自引率
5.80%
发文量
929
审稿时长
1.5 months
期刊介绍: The journal Chemistry of Materials focuses on publishing original research at the intersection of materials science and chemistry. The studies published in the journal involve chemistry as a prominent component and explore topics such as the design, synthesis, characterization, processing, understanding, and application of functional or potentially functional materials. The journal covers various areas of interest, including inorganic and organic solid-state chemistry, nanomaterials, biomaterials, thin films and polymers, and composite/hybrid materials. The journal particularly seeks papers that highlight the creation or development of innovative materials with novel optical, electrical, magnetic, catalytic, or mechanical properties. It is essential that manuscripts on these topics have a primary focus on the chemistry of materials and represent a significant advancement compared to prior research. Before external reviews are sought, submitted manuscripts undergo a review process by a minimum of two editors to ensure their appropriateness for the journal and the presence of sufficient evidence of a significant advance that will be of broad interest to the materials chemistry community.
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