Structural engineering of glass for regulating chemical surroundings of dopants

IF 5.7 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
Yuan Gao, Yikang Jiang, Xiaosong Lu and Zhiyong Yang
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Abstract

Optical gain materials activated by dopants are playing pivotal roles in fiber amplifiers, solid-state lasers and biological imaging. Achieving high photoluminescence (PL) efficiency in a stable matrix by regulating the chemical surroundings of dopants in an inert glass matrix remains a challenge. Here, we report a novel method for regulating the chemical surroundings of dopants by modulating the network structure of the glass matrix, achieving regulation of dopant PL efficiency. The luminescent properties of glass were adjusted not only by altering its composition, but also more importantly by controlled nanocrystallization. Furthermore, by utilizing lattice-site substitution engineering, the spectral shape and PL efficiency of active centers can be regulated by controlling the method of cation substitution at sub-nanometer scale.

Abstract Image

用于调节掺杂剂化学环境的玻璃结构工程
掺杂剂激活的光学增益材料在光纤放大器、固体激光器和生物成像等领域发挥着举足轻重的作用。通过调节惰性玻璃基质中掺杂剂的化学环境,在稳定的基质中实现高光致发光(PL)效率仍然是一个挑战。在这里,我们报道了一种通过调节玻璃基体的网络结构来调节掺杂剂化学环境的新方法,实现了对掺杂剂PL效率的调节。玻璃的发光性能不仅可以通过改变其组成来调节,更重要的是通过控制纳米晶化来调节。此外,利用晶格位取代工程,可以通过控制亚纳米尺度的阳离子取代方法来调节活性中心的光谱形状和PL效率。
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来源期刊
Journal of Materials Chemistry C
Journal of Materials Chemistry C MATERIALS SCIENCE, MULTIDISCIPLINARY-PHYSICS, APPLIED
CiteScore
10.80
自引率
6.20%
发文量
1468
期刊介绍: The Journal of Materials Chemistry is divided into three distinct sections, A, B, and C, each catering to specific applications of the materials under study: Journal of Materials Chemistry A focuses primarily on materials intended for applications in energy and sustainability. Journal of Materials Chemistry B specializes in materials designed for applications in biology and medicine. Journal of Materials Chemistry C is dedicated to materials suitable for applications in optical, magnetic, and electronic devices. Example topic areas within the scope of Journal of Materials Chemistry C are listed below. This list is neither exhaustive nor exclusive. Bioelectronics Conductors Detectors Dielectrics Displays Ferroelectrics Lasers LEDs Lighting Liquid crystals Memory Metamaterials Multiferroics Photonics Photovoltaics Semiconductors Sensors Single molecule conductors Spintronics Superconductors Thermoelectrics Topological insulators Transistors
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