David O. Juma , Sizwe J. Zamisa , Wisdom Munzeiwa , Bernard Omondi
{"title":"(Z)-N-(2,6-Dimethylphenyl)-1-[(2-methoxyphenyl)amino]methanimine oxide methanol monosolvate","authors":"David O. Juma , Sizwe J. Zamisa , Wisdom Munzeiwa , Bernard Omondi","doi":"10.1107/S2414314624009891","DOIUrl":null,"url":null,"abstract":"<div><div>The crystal structure of a zwitterionic unsymmetrical hydroxyformamidine methanol monosolvate is reported.</div></div><div><div>In the title solvate, C<sub>16</sub>H<sub>18</sub>N<sub>2</sub>O<sub>2</sub>·CH<sub>4</sub>O, the dihedral angles between the formamidine backbone and the pendant 2-methoxyphenyl and 2,6-dimethylphenyl groups are 14.84 (11) and 81.61 (12)°, respectively. In the crystal, the components are linked by C—H⋯O, O—H⋯O and C—H⋯ π hydrogen bonds, generating a supramolecular chain that extends along the crystallographic <em>a-</em>axis direction.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (212KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 10","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11660174/pdf/","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314624001111","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
The crystal structure of a zwitterionic unsymmetrical hydroxyformamidine methanol monosolvate is reported.
In the title solvate, C16H18N2O2·CH4O, the dihedral angles between the formamidine backbone and the pendant 2-methoxyphenyl and 2,6-dimethylphenyl groups are 14.84 (11) and 81.61 (12)°, respectively. In the crystal, the components are linked by C—H⋯O, O—H⋯O and C—H⋯ π hydrogen bonds, generating a supramolecular chain that extends along the crystallographic a-axis direction.