Accessing mixed cluster rare-earth MOFs with reduced connectivity via linker expansion and desymmetrization: co-assembly of 6-c and 10-c hexanuclear clusters in RE-stc-MOF-1†

IF 5.7 2区材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY

Journal of Materials Chemistry C Pub Date : 2024-12-03 DOI:10.1039/D4TC03317E

Edward Loukopoulos, Constantinos Tsangarakis, Konstantinos G. Froudas, Maria Vassaki, Giasemi K. Angeli and Pantelis N. Trikalitis

引用次数: 0

Abstract

MOFs based on hexanuclear rare-earth (RE) clusters with reduced connectivity (<12) are rare. The co-assembly of RE clusters with distinct reduced connectivity provides access to novel structures. We report a new family of MOFs denoted as RE-stc-MOF-1, displaying a unique (3,3,3,3,6,10)-connected network, based on 6-c and 10-c RE hexanuclear clusters.

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来源期刊

Journal of Materials Chemistry C MATERIALS SCIENCE, MULTIDISCIPLINARY-PHYSICS, APPLIED

CiteScore

10.80

自引率

6.20%

发文量

1468

期刊介绍： The Journal of Materials Chemistry is divided into three distinct sections, A, B, and C, each catering to specific applications of the materials under study: Journal of Materials Chemistry A focuses primarily on materials intended for applications in energy and sustainability. Journal of Materials Chemistry B specializes in materials designed for applications in biology and medicine. Journal of Materials Chemistry C is dedicated to materials suitable for applications in optical, magnetic, and electronic devices. Example topic areas within the scope of Journal of Materials Chemistry C are listed below. This list is neither exhaustive nor exclusive. Bioelectronics Conductors Detectors Dielectrics Displays Ferroelectrics Lasers LEDs Lighting Liquid crystals Memory Metamaterials Multiferroics Photonics Photovoltaics Semiconductors Sensors Single molecule conductors Spintronics Superconductors Thermoelectrics Topological insulators Transistors