{"title":"Overview of Tacticity Control in Radical Polymerization.","authors":"Hana Elhaddad, Daryl W Yee","doi":"10.2533/chimia.2024.831","DOIUrl":null,"url":null,"abstract":"<p><p>The stereoregularity of a polymer plays a key role in determining its properties. While stereocontrol can easily be achieved in coordination and ionic polymerization, it remains a challenge with radical polymerization. Considering the ubiquity and versatility of radical polymerization, significant efforts have been made over the past 50 years to address this issue. In this mini review, we highlight some of the strategies that have been developed to enable stereospecific radical polymerization, from the use of Lewis acid additives to the application of high electric fields. We hope that this review will provide the reader with a comprehensive overview of the current state of the art and equip them with the foundational knowledge needed to explore new avenues in this domain.</p>","PeriodicalId":9957,"journal":{"name":"Chimia","volume":"78 12","pages":"831-835"},"PeriodicalIF":1.1000,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chimia","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.2533/chimia.2024.831","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The stereoregularity of a polymer plays a key role in determining its properties. While stereocontrol can easily be achieved in coordination and ionic polymerization, it remains a challenge with radical polymerization. Considering the ubiquity and versatility of radical polymerization, significant efforts have been made over the past 50 years to address this issue. In this mini review, we highlight some of the strategies that have been developed to enable stereospecific radical polymerization, from the use of Lewis acid additives to the application of high electric fields. We hope that this review will provide the reader with a comprehensive overview of the current state of the art and equip them with the foundational knowledge needed to explore new avenues in this domain.
期刊介绍：
CHIMIA, a scientific journal for chemistry in the broadest sense covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.
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