Structure and Properties of Hybrid Composites Based on Dressed Aluminosilicate Microspheres and Polypropylene Graft Copolymer with Methacrylic Acid

IF 0.6 4区 化学 Q4 CHEMISTRY, APPLIED
N. T. Kakhramanov, R. V. Kurbanova
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引用次数: 0

Abstract

The paper presents the results of a study of the influence of the dressing process of a hollow aluminosilicate microsphere on the structural features and regulaties of changes in the main physical and mechanical characteristics of composites based on polypropylene graft copolymer with methacrylic acid. Organosilicon compound АГМ-9 (γ-aminopropyltriethoxysilane) was used as a dressing size. The mechanism of the sol-gel reaction in the process of dressing the surface of microspheres is given. The introduction of dressed microspheres into the composition of the graft copolymer made it possible to obtain hybrid composites with improved physical and mechanical properties. The most probable mechanism for the formation of the structure of hybrid composites with the formation of a three-level cross-linked spatial structure - “interpenetrating networks” is considered. The use of the method of thermomechanical studies of dressed and undressed composites confirmed the assumption of the formation of interpenetrating networks.

Abstract Image

基于压制硅酸铝微球和聚丙烯与甲基丙烯酸接枝共聚物的混合复合材料的结构与性能
本文介绍了中空硅酸铝微球敷料工艺对基于聚丙烯与甲基丙烯酸接枝共聚物的复合材料的结构特征和主要物理机械特性变化的影响的研究结果。有机硅化合物АГМ-9(γ-氨基丙基三乙氧基硅烷)被用作敷料。给出了微球表面敷料过程中溶胶-凝胶反应的机理。在接枝共聚物的成分中引入敷料微球,可以获得物理和机械性能更好的混合复合材料。研究考虑了形成三级交联空间结构--"互穿网络 "的混合复合材料结构的最可能的形成机制。使用热力学方法对包扎和未包扎的复合材料进行研究,证实了形成互穿网络的假设。
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来源期刊
CiteScore
1.60
自引率
11.10%
发文量
63
审稿时长
2-4 weeks
期刊介绍: Russian Journal of Applied Chemistry (Zhurnal prikladnoi khimii) was founded in 1928. It covers all application problems of modern chemistry, including the structure of inorganic and organic compounds, kinetics and mechanisms of chemical reactions, problems of chemical processes and apparatus, borderline problems of chemistry, and applied research.
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