Cerium-Catalyzed Ritter-type C-H Amination of Alkylarenes

IF 2.5 3区化学 Q2 CHEMISTRY, ORGANIC

European Journal of Organic Chemistry Pub Date : 2024-12-17 DOI:10.1002/ejoc.202400935

Renpeng Guan, Tianlin Wang, Elliot L. Bennett, Zhiliang Huang, Jianliang Xiao

引用次数: 0

Abstract

Reported here is a photocatalytic strategy for Ritter-type C-H amination of alkylarenes with nitriles. Under the irradiation of blue light and the catalysis of a simple Ce(III) salt, alkylarenes were brominated by CBr3COOH and thereby channeled to the normal Ritter pathway to afford amide products. A wide range of alkylarenes and nitriles were tolerated, with a few equivalents of a nitrile being feasible.

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本文报告的是一种光催化策略，用于烷基烯类与腈类的里特式 C-H 氨化反应。在蓝光照射和简单的 Ce（III）盐催化下，烷基烯烃被 CBr3COOH 溴化，从而进入正常的里特路径，得到酰胺产物。可容许的烷基烯烃和腈的范围很广，几当量的腈也是可行的。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

European Journal of Organic Chemistry 化学-有机化学

CiteScore

5.40

自引率

3.60%

发文量

752

审稿时长

1 months

期刊介绍： The European Journal of Organic Chemistry (2019 ISI Impact Factor 2.889) publishes Full Papers, Communications, and Minireviews from the entire spectrum of synthetic organic, bioorganic and physical-organic chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form two leading journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry: Liebigs Annalen Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry.