Selectivity Promotion of Cu by Manganese Oxide in Hydrogenative Ring Opening of Furfural to Pentanediols

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2024-12-13 DOI:10.1039/d4cc05247a

Huixiang Li, Huayang Li, Jun Shen, Changhui Liang, Xiaoqiang Zhang, Wei Zhang, Yongxin Li, Z. Conrad Zhang

引用次数: 0

Abstract

This work reports a targeted activation of C-O-C of furfural alcohol (FA) to produce pentanediols (PeDs) over MnO2 modified Cu. Infrared spectroscopy revealed the strong interaction of furan ring and C-O-C of FA with catalyst surface in a preferred flat adsorption configuration, thus facilitating the activation and cleavage of C-O-C to form PeDs.

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这项研究报告了在二氧化锰修饰的铜上有针对性地活化糠醛醇（FA）的 C-O-C 生成戊二醇（PeDs）的过程。红外光谱显示，呋喃环和糠醛的 C-O-C 与催化剂表面有很强的相互作用，形成一种优先的平面吸附构型，从而促进了 C-O-C 的活化和裂解，形成 PeDs。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.