Multi-fold catalytic activities of Ni nanoparticles supported on TiN for improving the hydrogen storage of NaAlH4

IF 6.3 2区 材料科学 Q2 CHEMISTRY, PHYSICAL
Ning Ma, Xiaobo Ma, Ling Ma, Xiaomeng Wang, Zhijie Cao
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Abstract

The high desorption temperature and sluggish kinetics of NaAlH4 limit its applications in hydrogen storage. To address these issues, a Ni nanoparticles-loaded TiN composite catalyst with excellent thermodynamic stability and catalytic activity was constructed. The addition of 5 wt% Ni10@TiN reduced the initial dehydrogenation temperature of NaAlH4 to 81 °C, and a total amount of 5.4 wt% H2 could be released within 20 min at 170 °C. The activation energies for the two-step dehydrogenations were significantly reduced to 66.3 kJ/mol and 81.4kJ/mol, respectively, which were 43 % and 36 % lower than that of pure NaAlH4. Experimental results and theoretical calculations suggested that these remarkable improvements were originated from the grain refinement of NaAlH4 and multi-fold catalytic activities of Ni10@TiN catalyst like providing catalytic active sites, facilitating the breaking of Al-H and H-H bonds, and increasing hydrogen diffusion channels. These findings may offer new ideas for designing high-efficiency catalysts for solid-state hydrogen storage materials.

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来源期刊
Applied Surface Science
Applied Surface Science 工程技术-材料科学:膜
CiteScore
12.50
自引率
7.50%
发文量
3393
审稿时长
67 days
期刊介绍: Applied Surface Science covers topics contributing to a better understanding of surfaces, interfaces, nanostructures and their applications. The journal is concerned with scientific research on the atomic and molecular level of material properties determined with specific surface analytical techniques and/or computational methods, as well as the processing of such structures.
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阿拉丁 nickel acetate
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