Which Flavor of 9,10-Bis(phenylethynyl)Anthracene is Best for Perovskite-Sensitized Triplet–Triplet Annihilation?

IF 24.4 1区 材料科学 Q1 CHEMISTRY, PHYSICAL
Colette M. Sullivan, Adrienn M. Szucs, Andrew P. Cantrell, Katherine E. Shulenberger, Theo Siegrist, Lea Nienhaus
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Abstract

The lack of viable solid-state annihilators is one of the greatest hurdles in perovskite-sensitized triplet–triplet annihilation upconversion (UC). Unfavorable singlet and triplet energy surfaces in the solid state have limited the successful implementation of many conventional solution-based annihilators. To date, rubrene is still the best-performing annihilator; however, this comes at the cost of a limited apparent anti-Stokes shift. To this point, anthracene derivatives are promising candidates to increase the apparent anti-Stokes shift. The well-known green glowstick dye 9,10-(bisphenylethynyl)anthracene (BPEA) and its chlorinated derivatives have already shown promise in solution-based UC applications. Due to favorable band alignment of the perovskite and triplet energy levels of BPEA, it is conceivable that a wide variety of BPEA derivatives can be compatible with the perovskite-based UC system. Here, the properties of the parent molecule BPEA and its derivatives 1-chloro-9,10-(bisphenylethynyl)anthracene and 2-chloro-9,10-(bisphenylethynyl)anthracene are investigated. Despite similar optical properties in solution, the different molecules exhibit vastly different properties in thin films. UC studies in lead halide perovskite/BPEA bilayer devices demonstrate the importance of intermolecular coupling on the resulting properties of the upconverted emission.

Abstract Image

哪种口味的9,10-二(苯乙基)蒽最适合钙钛矿敏化的三重-三重湮灭?
缺乏可行的固态湮灭体是钙钛矿敏化三重态湮灭上转换(UC)的最大障碍之一。在固态中不利的单线态和三重态能量表面限制了许多传统的基于溶液的湮灭器的成功实现。迄今为止,rubrene仍然是性能最好的歼灭剂;然而,这是以有限的反斯托克斯转变为代价的。在这一点上,蒽衍生物有望增加明显的反斯托克斯位移。众所周知的绿色荧光棒染料9,10-(双苯乙基)蒽(BPEA)及其氯化衍生物已经在基于溶液的UC应用中显示出前景。由于BPEA的钙钛矿和三重态能级具有良好的能带排列,可以想象,多种BPEA衍生物可以与钙钛矿基UC体系兼容。本文研究了母体分子BPEA及其衍生物1-氯-9,10-(双苯乙基)蒽和2-氯-9,10-(双苯乙基)蒽的性质。尽管溶液中的光学性质相似,但不同的分子在薄膜中表现出截然不同的性质。卤化铅钙钛矿/BPEA双分子层器件的UC研究证明了分子间耦合对上转换发射特性的重要性。
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来源期刊
Advanced Energy Materials
Advanced Energy Materials CHEMISTRY, PHYSICAL-ENERGY & FUELS
CiteScore
41.90
自引率
4.00%
发文量
889
审稿时长
1.4 months
期刊介绍: Established in 2011, Advanced Energy Materials is an international, interdisciplinary, English-language journal that focuses on materials used in energy harvesting, conversion, and storage. It is regarded as a top-quality journal alongside Advanced Materials, Advanced Functional Materials, and Small. With a 2022 Impact Factor of 27.8, Advanced Energy Materials is considered a prime source for the best energy-related research. The journal covers a wide range of topics in energy-related research, including organic and inorganic photovoltaics, batteries and supercapacitors, fuel cells, hydrogen generation and storage, thermoelectrics, water splitting and photocatalysis, solar fuels and thermosolar power, magnetocalorics, and piezoelectronics. The readership of Advanced Energy Materials includes materials scientists, chemists, physicists, and engineers in both academia and industry. The journal is indexed in various databases and collections, such as Advanced Technologies & Aerospace Database, FIZ Karlsruhe, INSPEC (IET), Science Citation Index Expanded, Technology Collection, and Web of Science, among others.
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