One-dimensional heterometallic Bi/Ag and Sb/Ag bromometalates(iii): structures, thermal stability and optical properties†

IF 2.6 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
CrystEngComm Pub Date : 2024-11-11 DOI:10.1039/D4CE01083C
Irina A. Shentseva, Andrey N. Usoltsev, Nikita A. Korobeynikov, Maxim N. Sokolov and Sergey A. Adonin
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引用次数: 0

Abstract

Silver-containing heterometallic bromobismuthates(III) (3-BrPyC3){[BiAgBr6]} (1) and (ImC4){[BiAgBr6]} (2) and bromoantimonate (ImC4)3{[Sb3Ag2Br17]} (3) (3-BrPyC3 – 1,6-bis(3-bromopyridin-1-ium)propane dication, ImC4 – diprotonated 1,4-bis(1H-imidazol-1-yl)butane) were synthesized. All compounds are composed of infinite chains, featuring yet unprecedented in halometalate(III) chemistry structural types. 1–3 reveal relatively high (>200 °C) thermal stability. Optical band gaps for 1–3 were estimated from UV-vis spectroscopy data.

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来源期刊
CrystEngComm
CrystEngComm 化学-化学综合
CiteScore
5.50
自引率
9.70%
发文量
747
审稿时长
1.7 months
期刊介绍: Design and understanding of solid-state and crystalline materials
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