Eric M Njogu, David O Juma, Sizwe J Zamisa, Bernard Omondi, Vincent O Nyamori
{"title":"4'-(2-Meth-oxy-phen-yl)-2,2':6',2''-terpyridine.","authors":"Eric M Njogu, David O Juma, Sizwe J Zamisa, Bernard Omondi, Vincent O Nyamori","doi":"10.1107/S241431462401143X","DOIUrl":null,"url":null,"abstract":"<p><p>In the title compound, C<sub>22</sub>H<sub>17</sub>N<sub>3</sub>O, the N atoms of the pyridine rings exhibit a typical <i>trans</i>-<i>trans</i> arrangement: the dihedral angles between the central pyridine ring and the peripheral rings are 22.24 (4) and 2.38 (4)°. In the crystal, pairwise C-H⋯N hydrogen bonds form inversion dimers described by an <i>R</i> <sup>2</sup> <sub>2</sub>(6) graph set descriptor, which further inter-act through C-H⋯π and π-π inter-actions, creating a two-dimensional supra-molecular network propagating in the <i>bc</i> plane.</p>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 Pt 11","pages":"x241143"},"PeriodicalIF":0.0000,"publicationDate":"2024-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11618872/pdf/","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1107/S241431462401143X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/11/1 0:00:00","PubModel":"eCollection","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
In the title compound, C22H17N3O, the N atoms of the pyridine rings exhibit a typical trans-trans arrangement: the dihedral angles between the central pyridine ring and the peripheral rings are 22.24 (4) and 2.38 (4)°. In the crystal, pairwise C-H⋯N hydrogen bonds form inversion dimers described by an R22(6) graph set descriptor, which further inter-act through C-H⋯π and π-π inter-actions, creating a two-dimensional supra-molecular network propagating in the bc plane.