{"title":"Nickel-Catalyzed Reductive Difunctionalization of BN-heterocyclic Olefins","authors":"Chaokun Li, Kui Yu, Kai Yang, Qiuling Song","doi":"10.1039/d4qo02032d","DOIUrl":null,"url":null,"abstract":"The difunctionalization of olefins as an effective synthetic strategy has garnered significant attention among organic synthetic chemists, thus enabling complex molecular scaffolds to be assembled in a single step from readily accessible feedstock chemicals. Herein, a nickel-catalyzed reductive difunctionalization of BN-heterocyclic alkenes has been developed. A variety of BN-heterocycles were synthesized utilizing the specific characteristics of selected difunctionalization reactions, thereby facilitating the synthesis of a wider range of BN-heterocycles through further conversions and applications.","PeriodicalId":97,"journal":{"name":"Organic Chemistry Frontiers","volume":"18 1","pages":""},"PeriodicalIF":4.6000,"publicationDate":"2024-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic Chemistry Frontiers","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4qo02032d","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
The difunctionalization of olefins as an effective synthetic strategy has garnered significant attention among organic synthetic chemists, thus enabling complex molecular scaffolds to be assembled in a single step from readily accessible feedstock chemicals. Herein, a nickel-catalyzed reductive difunctionalization of BN-heterocyclic alkenes has been developed. A variety of BN-heterocycles were synthesized utilizing the specific characteristics of selected difunctionalization reactions, thereby facilitating the synthesis of a wider range of BN-heterocycles through further conversions and applications.
期刊介绍:
Organic Chemistry Frontiers is an esteemed journal that publishes high-quality research across the field of organic chemistry. It places a significant emphasis on studies that contribute substantially to the field by introducing new or significantly improved protocols and methodologies. The journal covers a wide array of topics which include, but are not limited to, organic synthesis, the development of synthetic methodologies, catalysis, natural products, functional organic materials, supramolecular and macromolecular chemistry, as well as physical and computational organic chemistry.