1D Polymeric Iodoantimonates(III) with 1-Methylpyridinium and 3-Bromo-1-methylpyridinium Cations: Structures and Properties

IF 1.1 3区 化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR
I. A. Shentseva, A. N. Usol’tsev, N. A. Korobeinikov, S. A. Adonin
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引用次数: 0

Abstract

The reactions of SbI3 with iodides of cations of the pyridinium family in a mixture of acetonitrile and acetone afford two polymeric iodoantimonate complexes: (1-MePy){[SbI4]} (I) and (3-Br-1-MePy){[SbI4]} (II). Specific features of the crystal structures are determined by X-ray diffraction (XRD). The thermal stability of compounds I and II is evaluated by thermogravimetry. The optical forbidden bandgaps are estimated from the diffuse reflectance spectra.

Abstract Image

含1-甲基吡啶和3-溴-1-甲基吡啶阳离子的1D聚合物碘锑酸盐(III):结构和性质
在乙腈和丙酮的混合物中,SbI3与吡啶族阳离子的碘化物反应得到两个聚合碘锑酸盐配合物:(1-MePy){[SbI4]} (I)和(3-Br-1-MePy){[SbI4]} (II)。用热重法评价了化合物I和II的热稳定性。从漫反射光谱中估计了光学禁带隙。
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来源期刊
Russian Journal of Coordination Chemistry
Russian Journal of Coordination Chemistry 化学-无机化学与核化学
CiteScore
2.40
自引率
15.80%
发文量
85
审稿时长
7.2 months
期刊介绍: Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.
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