Visible light-induced PPh₃/MI-promoted δ-C(sp³)-H chlorination and cyclization with N-chloro-arylsulfonamides via EDA complexes.

IF 2.9 3区化学 Q1 CHEMISTRY, ORGANIC

Organic & Biomolecular Chemistry Pub Date : 2024-12-03 DOI:10.1039/d4ob01484g

Xiaotao Qin, Hui Liu, Jinkai Hu, Chenglei Yang, Ao-Tong Shi, Qing-Long Lv, Jinhui Yang, Dianjun Li

引用次数: 0

Abstract

Triphenylphosphine, iodide and N-chloro-arylsulfonamides could generate amidyl radicals via EDA (Electron Donor-Acceptor) complexes under visible light irradiation, and this strategy enables the synthesis of valuable δ-chloro-arylsulfonamide and N-arylsulfonylpyrrolidine motifs in moderate yields. This blue LED-induced method utilizes more readily available reagents, providing advantages in terms of cost efficiency, broad substrate scope, and functional-group compatibility.

查看原文本刊更多论文

求助全文

约1分钟内获得全文求助全文

来源期刊

Organic & Biomolecular Chemistry 化学-有机化学

CiteScore

5.50

自引率

9.40%

发文量

1056

审稿时长

1.3 months

期刊介绍： Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.

Visible light-induced PPh3/MI-promoted δ-C(sp3)-H chlorination and cyclization with N-chloro-arylsulfonamides via EDA complexes.

Abstract

Visible light-induced PPh₃/MI-promoted δ-C(sp³)-H chlorination and cyclization with N-chloro-arylsulfonamides via EDA complexes.