Organic-inorganic hybrids: A comprehensive review on synthesis and their potential applications

IF 4.3 3区材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY

Materials Chemistry and Physics Pub Date : 2024-11-23 DOI:10.1016/j.matchemphys.2024.130181

Manjeshwara Nikshitha, Sarvajith Malali Sudhakara, Mangalpady Shivaprasad Shetty

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Abstract

Organic-inorganic hybrids highlight the advantages of the presence of organic compounds, due to their stability, flexibility, and adaptability, as well as the structural features of inorganic materials. This review delves into the interaction between conducting polymers (CPs) and metal oxides (MOs), showcasing their combined advantages in various sectors such as sensors, capacitors, catalysts, and fuel cells. This paper explores the synthesis methods of prominent CPs including Polypyrrole (PPy), Polyaniline (PANI), Poly(3,4-ethylene dioxythiophene) (PEDOT), and Polyindole (PIn), along with a spectrum of MOs like zinc oxide (ZnO), copper oxide (CuO), titanium dioxide (TiO₂), manganese dioxide (MnO₂), iron oxides (Fe₂O₃ and Fe₃O₄), and nickel oxide (NiO). Diverse preparation techniques such as chemical oxidative, emulsion, and interfacial polymerization for CPs have been reported. Hydrothermal, co-precipitation, and sol-gel methods have been studied to synthesize MOs. Advanced characterization techniques such as Field emission scanning electron microscopy (FESEM), Energy dispersive X-ray analysis (EDAX), Transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET) have been reported to study the structural and morphological aspects of CP-MO hybrids. These hybrids exhibit potential applications in sensors, biosensors, antimicrobial activity, energy storage devices, and photocatalysis. This review provides a comprehensive overview, which aims to explore the prospects and innovations in the area of organic-inorganic hybrids.

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有机-无机杂化物：合成及其潜在应用综述

有机-无机混合物因其稳定性、灵活性和适应性，以及无机材料的结构特征，凸显了有机化合物的优势。本综述深入探讨了导电聚合物（CPs）和金属氧化物（MOs）之间的相互作用，展示了它们在传感器、电容器、催化剂和燃料电池等不同领域的综合优势。本文探讨了包括聚吡咯（PPy）、聚苯胺（PANI）、聚（3,4-乙烯二氧噻吩）（PEDOT）和聚吲哚（PIn）在内的主要导电聚合物的合成方法、以及氧化锌（ZnO）、氧化铜（CuO）、二氧化钛（TiO2）、二氧化锰（MnO2）、氧化铁（Fe2O3 和 Fe3O4）和氧化镍（NiO）等各种氧化膜。有报道称，氯化石蜡的制备技术多种多样，如化学氧化、乳液聚合和界面聚合。还研究了水热法、共沉淀法和溶胶-凝胶法来合成 MOs。有报告称，场发射扫描电子显微镜（FESEM）、能量色散 X 射线分析（EDAX）、透射电子显微镜（TEM）、布鲁诺-艾美特-泰勒（BET）等先进的表征技术可用于研究 CP-MO 混合物的结构和形态。这些杂化物在传感器、生物传感器、抗菌活性、储能装置和光催化等方面具有潜在的应用前景。本综述提供了一个全面的概述，旨在探索有机-无机杂化物领域的前景和创新。

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来源期刊

Materials Chemistry and Physics 工程技术-材料科学：综合

CiteScore

8.70

自引率

4.30%

发文量

1515

审稿时长

69 days

期刊介绍： Materials Chemistry and Physics is devoted to short communications, full-length research papers and feature articles on interrelationships among structure, properties, processing and performance of materials. The Editors welcome manuscripts on thin films, surface and interface science, materials degradation and reliability, metallurgy, semiconductors and optoelectronic materials, fine ceramics, magnetics, superconductors, specialty polymers, nano-materials and composite materials.