Comparison of Various Methods and Detectors to Determine Isotherms Using Self-Packed Columns

IF 1.5 4区 工程技术 Q3 ENGINEERING, CHEMICAL
Caroline Heiduk, Xiushi Miao, Prof. Dr.-Ing. Stephan Scholl
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引用次数: 0

Abstract

The study aims to determine adsorption isotherms through dynamic methods, including elution by characteristic point (ECP) and frontal analysis (FA), using a model system of beta zeolite and an aqueous sorbitol solution. The investigation specifically focuses on self-packed fixed-bed columns with a low number of theoretical plates Nt. It details the packing method optimization for these columns and identifies key challenges. Ultraviolet-visible (UV/Vis) and refractive index (RI) detectors, including parameters such as rise time trise and wavelength λ, are thoroughly compared in this study. Various models are assessed for their appropriateness in predicting the isotherms. The study's practical implications have the potential to enhance research and industrial applications in the field of adsorption, particularly with regard to the optimization of adsorbent materials and detection methods.

Abstract Image

比较使用自填料色谱柱测定等温线的各种方法和检测器
本研究旨在利用 beta 沸石和山梨醇水溶液模型系统,通过动态方法(包括特征点洗脱(ECP)和正面分析(FA))确定吸附等温线。研究特别关注理论板数 Nt 较少的自填料固定床色谱柱。报告详细介绍了这些色谱柱的填料优化方法,并指出了面临的主要挑战。本研究对紫外-可见 (UV/Vis) 和折射率 (RI) 检测器,包括上升时间 trise 和波长 λ 等参数进行了全面比较。评估了各种模型在预测等温线方面的适当性。这项研究的实际意义可能会促进吸附领域的研究和工业应用,特别是在吸附剂材料和检测方法的优化方面。
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来源期刊
Chemie Ingenieur Technik
Chemie Ingenieur Technik 工程技术-工程:化工
CiteScore
3.40
自引率
15.80%
发文量
601
审稿时长
3-6 weeks
期刊介绍: Die Chemie Ingenieur Technik ist die wohl angesehenste deutschsprachige Zeitschrift für Verfahrensingenieure, technische Chemiker, Apparatebauer und Biotechnologen. Als Fachorgan von DECHEMA, GDCh und VDI-GVC gilt sie als das unverzichtbare Forum für den Erfahrungsaustausch zwischen Forschern und Anwendern aus Industrie, Forschung und Entwicklung. Wissenschaftlicher Fortschritt und Praxisnähe: Eine Kombination, die es nur in der CIT gibt!
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