In Situ Transmission Electron Microscopy Advancing Cathodal Dynamic Visualization in All-Solid-State Battery

IF 19.3 1区材料科学 Q1 CHEMISTRY, PHYSICAL

ACS Energy Letters Pub Date : 2024-10-09 DOI:10.1021/acsenergylett.4c0187810.1021/acsenergylett.4c01878

Yue Zheng, Lei Hu, Wenru Li, Tianpeng Huang, Jun Ma*, Shanmu Dong* and Guanglei Cui*,

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Abstract

All-solid-state battery (ASSB) technology is one of the most promising approaches to energy storage due to its great safety and energy density. However, the detrimental effects of cathodal structure/morphology/composition/conductivity evolution on electrochemical performance significantly restrict the development of ASSBs. To elaborately investigate these cathodal dynamic evolution processes and deterioration mechanisms of ASSBs, in situ transmission electron microscopy (TEM) technology has been extensively introduced into the ASSB research. This paper discusses the latest important scientific discoveries toward cathodal dynamic evolution in multitype ASSBs through in situ TEM and highlights key challenges for in situ TEM to analyze ASSB cathodes with a higher spatial resolution. Lastly, insights for future directions of in situ TEM monitoring multiscale electro-chemo-mechanical evolution of ASSBs are prospectively provided. This Review will deepen the fundamental understanding of cathodal dynamic mechanisms and open new opportunities for the optimization and development of in situ TEM in ASSBs.

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原位透射电子显微镜推进全固态电池的阴极动态可视化

全固态电池（ASSB）技术具有极高的安全性和能量密度，是最有前途的储能方法之一。然而，阴极结构/形态/组成/电导率演化对电化学性能的不利影响极大地限制了全固态电池的发展。为了详细研究这些阴极动态演化过程和 ASSB 的劣化机制，原位透射电子显微镜（TEM）技术已被广泛引入 ASSB 研究中。本文讨论了通过原位 TEM 对多类型 ASSB 阴极动态演化的最新重要科学发现，并强调了原位 TEM 以更高空间分辨率分析 ASSB 阴极所面临的关键挑战。最后，还展望了原位 TEM 监测 ASSB 多尺度电化学机械演变的未来发展方向。本综述将加深对阴极动态机制的基本理解，并为 ASSB 原位 TEM 的优化和发展带来新的机遇。

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来源期刊

ACS Energy Letters Energy-Renewable Energy, Sustainability and the Environment

CiteScore

31.20

自引率

5.00%

发文量

469

审稿时长

1 months

期刊介绍： ACS Energy Letters is a monthly journal that publishes papers reporting new scientific advances in energy research. The journal focuses on topics that are of interest to scientists working in the fundamental and applied sciences. Rapid publication is a central criterion for acceptance, and the journal is known for its quick publication times, with an average of 4-6 weeks from submission to web publication in As Soon As Publishable format. ACS Energy Letters is ranked as the number one journal in the Web of Science Electrochemistry category. It also ranks within the top 10 journals for Physical Chemistry, Energy & Fuels, and Nanoscience & Nanotechnology. The journal offers several types of articles, including Letters, Energy Express, Perspectives, Reviews, Editorials, Viewpoints and Energy Focus. Additionally, authors have the option to submit videos that summarize or support the information presented in a Perspective or Review article, which can be highlighted on the journal's website. ACS Energy Letters is abstracted and indexed in Chemical Abstracts Service/SciFinder, EBSCO-summon, PubMed, Web of Science, Scopus and Portico.