Antiaromatic Metallacyclopentatriene Complexes

IF 14.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Journal of the American Chemical Society Pub Date : 2024-11-04 DOI:10.1021/jacs.4c1414110.1021/jacs.4c14141

Bingjie Fu, Yarong Wang, Yue Zhao, Yang Li*, Wenfeng Jiang* and Wei Bai*,

引用次数: 0

Abstract

There is no report on the (anti)aromaticity of metallacyclopentatrienes, one kind of common and important five-membered metallacycles. This work presents the novel synthesis of osmium cis-biscarbene complexes and their oxidation to osmacyclopentatrienes. The osmacyclopentatriene unit is antiaromatic, as revealed by experimental and theoretical studies. This finding provides new insight into the discovery of antiaromatic species.

Abstract Image

查看原文本刊更多论文

反芳香族金属杂环戊三烯络合物

金属环戊三烯是一种常见而重要的五元金属环，目前还没有关于金属环戊三烯（反）芳香性的报道。这项研究提出了锇顺式二碳化络合物的新合成方法，并将其氧化为锇杂环戊三烯。实验和理论研究表明，锇杂环戊三烯单元是反芳香族的。这一发现为发现反芳香族物种提供了新的视角。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Journal of the American Chemical Society 化学-化学综合

CiteScore

24.40

自引率

6.00%

发文量

2398

审稿时长

1.6 months

期刊介绍： The flagship journal of the American Chemical Society, known as the Journal of the American Chemical Society (JACS), has been a prestigious publication since its establishment in 1879. It holds a preeminent position in the field of chemistry and related interdisciplinary sciences. JACS is committed to disseminating cutting-edge research papers, covering a wide range of topics, and encompasses approximately 19,000 pages of Articles, Communications, and Perspectives annually. With a weekly publication frequency, JACS plays a vital role in advancing the field of chemistry by providing essential research.