Polymeric Charge-Transporting Materials for Inverted Perovskite Solar Cells

IF 27.4 1区材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Advanced Materials Pub Date : 2024-11-13 DOI:10.1002/adma.202412327

Xiaodong Hu, Lingyuan Wang, Siwei Luo, He Yan, Shangshang Chen

{"title":"Polymeric Charge-Transporting Materials for Inverted Perovskite Solar Cells","authors":"Xiaodong Hu, Lingyuan Wang, Siwei Luo, He Yan, Shangshang Chen","doi":"10.1002/adma.202412327","DOIUrl":null,"url":null,"abstract":"Inverted perovskite solar cells (PSCs) hold exceptional promise as next-generation photovoltaic technology, where both perovskite absorbers and charge-transporting materials (CTMs) play critical roles in cell performance. In recent years, polymeric CTMs have played an important role in developing efficient, stable, and large-area inverted PSCs due to their unique properties of high conductivity, tunable structures, and mechanical flexibility. This review provides a comprehensive overview of polymeric CTMs used in inverted PSCs, encompassing polymeric hole transport materials (HTMs) and electron transport materials (ETMs). the relationship between their molecular structures, modification strategies are systematically summarized and analyzed for adjusting energy levels, and improving charge extraction, enabling a deep understanding of these widely used materials. The review also explores effective strategies for designing even more efficient polymeric CTMs. Finally, an outlook is proposed on the exciting research of novel polymeric CTMs, paving the way for their commercialized applications in PSCs.","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"216 1","pages":""},"PeriodicalIF":27.4000,"publicationDate":"2024-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/adma.202412327","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

Abstract

Inverted perovskite solar cells (PSCs) hold exceptional promise as next-generation photovoltaic technology, where both perovskite absorbers and charge-transporting materials (CTMs) play critical roles in cell performance. In recent years, polymeric CTMs have played an important role in developing efficient, stable, and large-area inverted PSCs due to their unique properties of high conductivity, tunable structures, and mechanical flexibility. This review provides a comprehensive overview of polymeric CTMs used in inverted PSCs, encompassing polymeric hole transport materials (HTMs) and electron transport materials (ETMs). the relationship between their molecular structures, modification strategies are systematically summarized and analyzed for adjusting energy levels, and improving charge extraction, enabling a deep understanding of these widely used materials. The review also explores effective strategies for designing even more efficient polymeric CTMs. Finally, an outlook is proposed on the exciting research of novel polymeric CTMs, paving the way for their commercialized applications in PSCs.

Abstract Image

查看原文本刊更多论文

用于反相包晶石太阳能电池的聚合物电荷传输材料

倒置型过氧化物太阳能电池（PSCs）有望成为下一代光伏技术，其中过氧化物吸收剂和电荷传输材料（CTMs）对电池性能起着至关重要的作用。近年来，聚合物 CTM 因其高导电性、可调结构和机械灵活性等独特性能，在开发高效、稳定和大面积倒置式 PSC 方面发挥了重要作用。本综述全面概述了倒置式 PSC 中使用的聚合物 CTM，包括聚合物空穴传输材料 (HTM) 和电子传输材料 (ETM)。本综述系统地总结和分析了这些材料分子结构之间的关系、调整能级和改善电荷萃取的改性策略，以便深入了解这些广泛使用的材料。综述还探讨了设计更高效聚合物 CTM 的有效策略。最后，还对新型聚合物 CTM 令人兴奋的研究进行了展望，为其在 PSC 中的商业化应用铺平了道路。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Advanced Materials 工程技术-材料科学：综合

CiteScore

43.00

自引率

4.10%

发文量

2182

审稿时长

2 months

期刊介绍： Advanced Materials, one of the world's most prestigious journals and the foundation of the Advanced portfolio, is the home of choice for best-in-class materials science for more than 30 years. Following this fast-growing and interdisciplinary field, we are considering and publishing the most important discoveries on any and all materials from materials scientists, chemists, physicists, engineers as well as health and life scientists and bringing you the latest results and trends in modern materials-related research every week.