Intermolecular Interactions and Isostructurality in the Series of Volatile Co(II), Ni(II), Cu(II), Pd(II), and Pt(II) Complexes with β-Ketoimines

IF 1.2 4区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Journal of Structural Chemistry Pub Date : 2024-11-11 DOI:10.1134/S0022476624100081

I. A. Baidina, N. V. Pervukhina, S. A. Gromilov

引用次数: 0

Abstract

We report a comparative crystal chemical analysis of volatile homoligand complexes of Co(II), Ni(II), Cu(II), Pd(II), and Pt(II) with β-ketoimines utilized as precursors in the preparation of oxide and metal film coatings for various purposes using chemical vapor deposition. The crystal structures and intermolecular interactions of β-ketoiminates with the general formula M(L)₂ (L = (R1-C(O)CH-C(N-R3)-R2)₂; R1, R2 = CH₃, CF₃, C(CH₃)₃, C(OCH₃)(CH₂)₂ in various combinations; R3 = H, CH₃) are studied.

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挥发性 Co(II)、Ni(II)、Cu(II)、Pd(II) 和 Pt(II) 与 β-酮亚胺配合物系列中的分子间相互作用和异构性

我们报告了 Co(II)、Ni(II)、Cu(II)、Pd(II) 和 Pt(II) 与 β-酮亚胺的挥发性同配体配合物的晶体化学比较分析，这些配合物可用作前体，利用化学气相沉积法制备各种用途的氧化物和金属薄膜涂层。研究了通式为 M(L)2 的 β-酮亚胺（L = (R1-C(O)CH-C(N-R3)-R2)2; R1, R2 = CH3, CF3, C(CH3)3, C(OCH3)(CH2)2 以各种组合形式存在；R3 = H, CH3）的晶体结构和分子间相互作用。

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来源期刊

Journal of Structural Chemistry 化学-无机化学与核化学

CiteScore

1.60

自引率

12.50%

发文量

142

审稿时长

8.3 months

期刊介绍： Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.