L. A. Zhukov, A. A. Lysova, D. G. Samsonenko, D. N. Dybtsev, V. P. Fedin
{"title":"A Series of Coordination Polymers Based on 4,8-Disulfo-2,6-Naphthalenedicarboxylic Acid","authors":"L. A. Zhukov, A. A. Lysova, D. G. Samsonenko, D. N. Dybtsev, V. P. Fedin","doi":"10.1134/S0022476624100196","DOIUrl":null,"url":null,"abstract":"<p>Five new metal-organic frameworks based on 4,8-disulfo-2,6-naphthalenedicarboxylic acid (H<sub>4</sub>dsndc) are obtained: [Cd<sub>2</sub>(dsndc)(dmf)<sub>6</sub>] (<b>1</b>), [Mn<sub>2</sub>(dsndc)(dmf)<sub>6</sub>] (<b>2</b>), [Zn<sub>2</sub>(dsndc)(dmf)<sub>6</sub>] (<b>3</b>), [Co<sub>2</sub>(dsndc)(dmf)<sub>6</sub>] (<b>4</b>), and [Cd<sub>2</sub>(dsndc)(dma)<sub>6</sub>] (<b>5</b>) (DMF = N,N-dimethylformamide, DMA = N,N-dimethylacetamide). The four of them (<b>1</b>–<b>4</b>) are isostructural layered coordination polymers. The structures of all compounds are determined by the single crystal X-ray diffraction analysis. Compounds <b>1</b>–<b>3</b> and <b>5</b> are obtained as chemically and phase-pure and are characterized by the standard complex of physicochemical techniques (powder XRD, IR, TGA, and CHN). Photoluminescence excitation and emission spectra are recorded for compound <b>3</b>, and a quantum yield of 18% is obtained.</p>","PeriodicalId":668,"journal":{"name":"Journal of Structural Chemistry","volume":"65 10","pages":"2111 - 2120"},"PeriodicalIF":1.2000,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Structural Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0022476624100196","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
Five new metal-organic frameworks based on 4,8-disulfo-2,6-naphthalenedicarboxylic acid (H4dsndc) are obtained: [Cd2(dsndc)(dmf)6] (1), [Mn2(dsndc)(dmf)6] (2), [Zn2(dsndc)(dmf)6] (3), [Co2(dsndc)(dmf)6] (4), and [Cd2(dsndc)(dma)6] (5) (DMF = N,N-dimethylformamide, DMA = N,N-dimethylacetamide). The four of them (1–4) are isostructural layered coordination polymers. The structures of all compounds are determined by the single crystal X-ray diffraction analysis. Compounds 1–3 and 5 are obtained as chemically and phase-pure and are characterized by the standard complex of physicochemical techniques (powder XRD, IR, TGA, and CHN). Photoluminescence excitation and emission spectra are recorded for compound 3, and a quantum yield of 18% is obtained.
期刊介绍：
Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
