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Structural transformation of silver(i)–thiolate coordination polymer film at solid–liquid interfaces†

IF 2.6 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
CrystEngComm Pub Date : 2024-10-28 DOI:10.1039/D4CE01023J
Myu Fukuoka, Yohei Takashima, Kensuke Akamatsu, Aude Demessence and Takaaki Tsuruoka
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Abstract

We report that the ligand-exchange reaction between [Ag(o-SPhCO2H)]n deposited on a solid substrate and the free p-HSPhCOOH ligand in solution results in crystal transformation from [Ag(o-SPhCO2H)]n to [Ag(p-SPhCO2H)]n on the substrate. Structural analysis revealed a structural transformation between CPs with different topologies via ligand exchange.

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银（i）-硫醇配位聚合物薄膜在固液界面上的结构转变†......
我们报告了沉积在固体基底上的[Ag(o-SPhCO2H)]n 与溶液中的游离 p-HSPhCOOH 配体之间的配体交换反应，导致基底上的[Ag(o-SPhCO2H)]n 晶体转变为[Ag(p-SPhCO2H)]n 晶体。结构分析表明，不同拓扑结构的 CP 之间通过配体交换发生了结构转变。
本文章由计算机程序翻译，如有差异，请以英文原文为准。
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来源期刊
CrystEngComm
CrystEngComm 化学-化学综合
CiteScore
5.50
自引率
9.70%
发文量
747
审稿时长
1.7 months
期刊介绍： Design and understanding of solid-state and crystalline materials
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