Exploring the effect of pressure on the crystal structure and caloric properties of the molecular ionic hybrid [(CH3)3NOH]2[CoCl4]†

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2024-11-01 DOI:10.1039/d4cc05125d

Pedro Dafonte-Rodríguez , Ignacio Delgado-Ferreiro , Javier García-Ben , Angel Ferradanes-Martínez , María Gelpi , Julian Walker , Charles James McMonagle , Socorro Castro-García , María Antonia Señarís-Rodríguez , Juan Manuel Bermúdez-García , Manuel Sánchez-Andújar

引用次数: 0

Abstract

The hybrid metal halide [(CH₃)₃NOH]₂CoCl₄ exhibits a first-order phase transition at T ∼ 343 K. Its crystal structure and caloric properties respond significantly to moderate pressures (1–1000 bar), demonstrating potential for applications in emerging solid-state refrigeration technologies.

Abstract Image

查看原文本刊更多论文

探索压力对分子离子杂化物 [(CH3)3NOH]2[CoCl4] 晶体结构和热性能的影响

混合金属卤化物[(CH₃)₃NOH]₂CoCl₄在 T~343 K 时出现一阶相变。其晶体结构和热量特性对中等压力（1-1000 巴）有显著反应，显示出在新兴固态制冷技术中的应用潜力。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.