{"title":"Reversible aminolysis: a new concept for postpolymerization modification†","authors":"Koki Kasai , Hideki Amii , Ryohei Kakuchi","doi":"10.1039/d4py00827h","DOIUrl":null,"url":null,"abstract":"<div><div>Despite the powerful synthetic benefits of aminolysis postpolymerization modifications (PPMs), conventional aminolysis PPMs suffer from irreversibility owing to the difficulties in cleaving amide bonds formed from activated esters and amines. In this study, we propose a new aminolysis PPM system that enables reversible reactions by regenerating activated esters.</div></div>","PeriodicalId":100,"journal":{"name":"Polymer Chemistry","volume":"15 45","pages":"Pages 4622-4626"},"PeriodicalIF":4.1000,"publicationDate":"2024-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1759995424003899","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
Despite the powerful synthetic benefits of aminolysis postpolymerization modifications (PPMs), conventional aminolysis PPMs suffer from irreversibility owing to the difficulties in cleaving amide bonds formed from activated esters and amines. In this study, we propose a new aminolysis PPM system that enables reversible reactions by regenerating activated esters.
期刊介绍:
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.