[Au]/[Ag]-catalysed synthesis of non-hydrolysable C-glycosides.

IF 2.9 3区 化学 Q1 CHEMISTRY, ORGANIC
Saptashwa Chakraborty, Daksh Telang, Bijoyananda Mishra, Srinivas Hotha
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引用次数: 0

Abstract

Many C-glycosides are found in natural products, drugs and small molecular probes. Herein, we report the synthesis of C-glycosides by the [Au]/[Ag]-catalysed activation of ethynylcyclohexyl glycosyl carbonate donors. This mild, catalytic, fast and high yielding protocol enables the synthesis of a diverse array of C-glycosides that were otherwise challenging to synthesize.

[金]/[银]催化的非水解 C-糖苷的合成。
在天然产物、药物和小分子探针中发现了许多 C-糖苷。在此,我们报告了通过[Au]/[Ag]催化活化乙炔基环己糖基碳酸酯供体合成 C-糖苷的过程。这种温和、催化、快速、高产的方法可以合成多种多样的 C-糖苷,而这些糖苷的合成在其他方法中是很难实现的。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Organic & Biomolecular Chemistry
Organic & Biomolecular Chemistry 化学-有机化学
CiteScore
5.50
自引率
9.40%
发文量
1056
审稿时长
1.3 months
期刊介绍: The international home of synthetic, physical and biomolecular organic chemistry.
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