Long-term leaching kinetics and solution chemistry of aqueous BaTiO3 powder suspensions: a numerical model supported experiment

IF 6.1 3区 医学 Q1 MATERIALS SCIENCE, BIOMATERIALS
Marcus Bentzen, Vojtěch Lindauer, Pavel Mokrý, Ragnhild Elizabeth Aune and Julia Glaum
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引用次数: 0

Abstract

The advent of lead-free perovskite materials with favorable toxicity profiles has made them candidates for in vivo and environmental applications. However, their tendency to leach A-site cations raises concerns about toxicity, catalytic efficiency, and slurry properties. The present study investigates the long-term leaching kinetics of BaTiO3 powders over 31 days in aqueous solutions of varying pH levels. Using ICP-MS analysis and a numerical model based on the Unreacted Shrinking Core (USC) principle. The study extends the understanding of BaTiO3 stability beyond previously reported timeframes. The findings highlight the material's long-term stability, with implications for biomedical and environmental applications.

Abstract Image

水性 BaTiO3 粉末悬浮液的长期浸出动力学和溶液化学性质:支持实验的数值模型。
具有良好毒性特征的无铅过氧化物材料的出现,使它们成为体内和环境应用的候选材料。然而,它们沥滤 A 位阳离子的倾向引起了人们对其毒性、催化效率和浆料特性的关注。本研究调查了 BaTiO3 粉末在不同 pH 值的水溶液中长达 31 天的长期浸出动力学。研究采用了 ICP-MS 分析和基于未反应收缩核心(USC)原理的数值模型。这项研究拓展了人们对 BaTiO3 稳定性的认识,使其超出了之前报告的时间范围。研究结果突出了该材料的长期稳定性,对生物医学和环境应用具有重要意义。
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来源期刊
Journal of Materials Chemistry B
Journal of Materials Chemistry B MATERIALS SCIENCE, BIOMATERIALS-
CiteScore
11.50
自引率
4.30%
发文量
866
期刊介绍: Journal of Materials Chemistry A, B & C cover high quality studies across all fields of materials chemistry. The journals focus on those theoretical or experimental studies that report new understanding, applications, properties and synthesis of materials. Journal of Materials Chemistry A, B & C are separated by the intended application of the material studied. Broadly, applications in energy and sustainability are of interest to Journal of Materials Chemistry A, applications in biology and medicine are of interest to Journal of Materials Chemistry B, and applications in optical, magnetic and electronic devices are of interest to Journal of Materials Chemistry C.Journal of Materials Chemistry B is a Transformative Journal and Plan S compliant. Example topic areas within the scope of Journal of Materials Chemistry B are listed below. This list is neither exhaustive nor exclusive: Antifouling coatings Biocompatible materials Bioelectronics Bioimaging Biomimetics Biomineralisation Bionics Biosensors Diagnostics Drug delivery Gene delivery Immunobiology Nanomedicine Regenerative medicine & Tissue engineering Scaffolds Soft robotics Stem cells Therapeutic devices
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