Chiral metal complexes: Design strategies for precision in asymmetric C–H activation

IF 6.5 1区化学 Q2 CHEMISTRY, PHYSICAL

Journal of Catalysis Pub Date : 2024-09-16 DOI:10.1016/j.jcat.2024.115756

Devesh Chandra , Tammana Sharma , Sarthi , Sachin , Upendra Sharma

引用次数: 0

Abstract

Due to their unique design, chiral metal complexes play an important role in asymmetric synthesis. In this review, we have focused on the design strategy and its applications in asymmetric C–H functionalization. This review provides a comprehensive overview of chronological development and the future perspective of chiral metal complexes. A brief discussion on the relation between the molecular design of transition metal complex and stereo differentiation in products leading to enantiomeric induction is also included.

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手性金属配合物：实现不对称 C-H 激活精确性的设计策略

由于设计独特，手性金属配合物在不对称合成中发挥着重要作用。在本综述中，我们重点介绍了手性金属配合物的设计策略及其在不对称 C-H 功能化中的应用。本综述全面概述了手性金属配合物的时序发展和未来展望。此外，还简要讨论了过渡金属配合物的分子设计与导致对映体诱导的产品立体分化之间的关系。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of Catalysis 工程技术-工程：化工

CiteScore

12.30

自引率

5.50%

发文量

447

审稿时长

31 days

期刊介绍： The Journal of Catalysis publishes scholarly articles on both heterogeneous and homogeneous catalysis, covering a wide range of chemical transformations. These include various types of catalysis, such as those mediated by photons, plasmons, and electrons. The focus of the studies is to understand the relationship between catalytic function and the underlying chemical properties of surfaces and metal complexes. The articles in the journal offer innovative concepts and explore the synthesis and kinetics of inorganic solids and homogeneous complexes. Furthermore, they discuss spectroscopic techniques for characterizing catalysts, investigate the interaction of probes and reacting species with catalysts, and employ theoretical methods. The research presented in the journal should have direct relevance to the field of catalytic processes, addressing either fundamental aspects or applications of catalysis.