Anastasiya Krech, Marharyta Laktsevich-Iskryk, Nora Deil, Mihhail Fokin, Mariliis Kimm, Maksim Ošeka
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引用次数: 0
Abstract
We report an iminium ion-promoted, asymmetric synthesis of cyclopropanes via an electrocatalytic, iodine-mediated ring closure. The mild, controlled electrochemical generation of electrophilic iodine species in catalytic quantities prevents organocatalyst deactivation, while also eliminating the need for halogenated reagents, thus simplifying traditional synthetic approaches.
期刊介绍:
ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.